Indium-mediated intermolecular alkyl radical addition to electron-deficient C=N bond and C=C bond in water

Organic Letters

Volumn 4, Issue 1, 2002, Pages 131-133

  Miyabe, Hideto ^a   Ueda, Masafumi ^a   Nishimura, Azusa ^a   Naito, Takeaki ^a  

^a KOBE PHARMACEUTICAL UNIVERSITY   (Japan)

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EID: 0000977631     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol017013h     Document Type: Article

References (57)

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52. As a comparison, the triethylborane-induced reaction of 1 was usually run by using a large amount of alkyl iodides (more than 30 equiv) to suppress the competitive reaction with ethyl radical generated from triethylborane. See ref 3a.
53. See Supporting Information for detail on the experimental procedures.
54. We previously reported the radical reaction based on an iodine atom transfer process. See: Miyabe, H.; Ueda, M.; Yoshioka, N.; Naito, T. Synlett 1999, 465.
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