Optimal control approach to suppression of radiationless transitions

Physical Review Letters

Volumn 93, Issue 9, 2004, Pages

  Sukharev, Maxim ^a   Seideman, Tamar ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EIGENVALUES AND EIGENFUNCTIONS; ELECTRONIC STRUCTURE; HAMILTONIANS; KINETIC ENERGY; PHOTOCHEMICAL REACTIONS; POTENTIAL ENERGY; PROBLEM SOLVING; QUANTUM THEORY; ROBUSTNESS (CONTROL SYSTEMS); ROTORS;

FIELD-FREE EVOLUTION; PERIODIC ORBITS; POLYATOMIC MOLECULES; RADIATIONLESS TRANSITIONS (RT);

OPTIMAL CONTROL SYSTEMS;

EID: 19544385590     PISSN: 00319007     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevLett.93.093004     Document Type: Article

References (36)

1. M. Montagna, O. Pilla and G. Viliani, Phys. Rev. Lett. 45, 1008 (2003).
2. (a) J. Jortner, S. A. Rice, and R. M. Hochstrasser, Adv. Photochem. 7, 149 (1969);
3. (b) K. F. Freed in Radiationless Processes in Molecules and Condensed Phases, edited by F. K. Fong (Springer, Berlin, 1976) p. 23;
4. (c) S. H. Lin, Radiationless Transitions (Academic, New York, 1980).
5. R. W. Schoenlein et al., Science 254, 412 (1991).
6. J. Jortner and M. Rather, Molecular Electronics (Blackwell, Oxford, 1997).
7. J. I. Pascual et al., Nature (London) 423, 525 (2003).
8. A. Demirplak and S. A Rice, J. Phys. Chem. A 107, 9937 (2003).
9. S. P. Shah, D. J. Tannor, and S. A. Rice, Phys. Rev. A 66 033405 (2002).
10. I. R. Solá et al., Phys. Rev. Lett. 85, 4241 (2000).
11. P. Král and M. Shapiro, Phys. Rev. Lett. 87, 183002 (2001).
12. For a review of the concept and application of stimulated Raman adiabatic passage as a method of producing complete population transfer see K. Bergmann, H. Theuer, and B. W. Shore, Rev. Mod. Phys. 70, 1003 (1998).
13. E. Frishman et al., J. Chem. Phys. 119, 7237 (2003).
14. Y. Fujimura et al., Chem. Phys. Lett. (to be published).
15. J. Jortner, R. D. Levine, and B. Pullman, in Mode Selective Chemistry, edited by E. D. Potter (Kluwer Academic, Dordrecht, 1991); J. L. Herek, et al., Nature (London) 355, 66 (1992).
16. J. Jortner, R. D. Levine, and B. Pullman, in Mode Selective Chemistry, edited by E. D. Potter (Kluwer Academic, Dordrecht, 1991); J. L. Herek, et al., Nature (London) 355, 66 (1992).
17. G. R. Van Hecke and K. K. Karukstis, A Guide to Lasers in Chemistry (Jones & Bartlett, Sudbury, MA, 1997).
18. A. G. Kofman and G. Kurizki, Phys. Rev. A 54, R3750 (1996); E. Frishman and M. Shapiro, ibid. 68, 032717 (2003).
19. A. G. Kofman and G. Kurizki, Phys. Rev. A 54, R3750 (1996); E. Frishman and M. Shapiro, ibid. 68, 032717 (2003).
20. W. Zhu and H. Rabitz, J. Chem. Phys. 118, 6751 (2003).
21. W. Zhu, J. Botina, and H. Rabitz, J. Chem. Phys. 108, 1953 (1998).
22. For an introduction to coherent control in general and optimal control theory in chemistry, in particular, see S. A. Rice and M. Zhao, Optical Control of Molecular Dynamics (John Wiley & Sons, New York, 2000); P. Brumer and M. Shapiro, Principles of the Quantum Control of Molecular Processes (Wiley InterScience, Hoboken, NJ, 2003); H. Rabitz et al., Science 288, 824 (2000).
23. For an introduction to coherent control in general and optimal control theory in chemistry, in particular, see S. A. Rice and M. Zhao, Optical Control of Molecular Dynamics (John Wiley & Sons, New York, 2000); P. Brumer and M. Shapiro, Principles of the Quantum Control of Molecular Processes (Wiley InterScience, Hoboken, NJ, 2003); H. Rabitz et al., Science 288, 824 (2000).
24. For an introduction to coherent control in general and optimal control theory in chemistry, in particular, see S. A. Rice and M. Zhao, Optical Control of Molecular Dynamics (John Wiley & Sons, New York, 2000); P. Brumer and M. Shapiro, Principles of the Quantum Control of Molecular Processes (Wiley InterScience, Hoboken, NJ, 2003); H. Rabitz et al., Science 288, 824 (2000).
25. I. Yamazaki, et al., Faraday Discuss. Chem. Soc. 75, 395 (1983).
26. V. Stert, P. Farmanara, and W. Radloff, J. Chem. Phys. 112, 4460 (2000).
27. L. Seidner, W. Domcke and W. von Niessen, Chem. Phys. Lett.,205, 117 (1993); C. Woywod et al., J. Chem. Phys. 100, 1400 (1994).
28. L. Seidner, W. Domcke and W. von Niessen, Chem. Phys. Lett.,205, 117 (1993); C. Woywod et al., J. Chem. Phys. 100, 1400 (1994).
29. The potential energy of
30. 10a.
31. 2 state and is neglected here.
32. S. Hahn and G. Stock, J. Phys. Chem. B 104, 1146 (2000).
33. V. Blancher, M. Z. Zgierski, T. Seideman, and A. Stolow, Nature (London) 401, 52 (1999).
34. E. J. Heller, Phys. Rev. Lett. 53, 1515 (1984); for a review, see J. Kaplan and E J. Heller, Ann. Phys. (N.Y.) 264, 171 (1998).
35. E. J. Heller, Phys. Rev. Lett. 53, 1515 (1984); for a review, see J. Kaplan and E J. Heller, Ann. Phys. (N.Y.) 264, 171 (1998).
36. T. C. Weinacht et al., Chem. Phys. Lett. 344, 333 (2001).