Changing mixed-valence state of hexacobalt cluster by substituting central metal ion and by electrochemical reduction - Different mixed-valence states of [M{Co(prolinato)2}6]4+(M = Ba2+ and La3+)

Chemistry Letters

Volumn 34, Issue 3, 2005, Pages 300-301

  Komiyama, Takashi ^a   Igarashi, Satoshi ^a   Hoshino, Yoshimasa ^b   Yukawa, Yasuhiko ^a  

^a NIIGATA UNIVERSITY   (Japan)

^b NAGASAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BARIUM DERIVATIVE; COBALT COMPLEX; LANTHANIDE;

ARTICLE; CRYSTALLIZATION; ELECTROCHEMICAL ANALYSIS; MOLECULAR PHYSICS; OXIDATION; SUBSTITUTION REACTION;

EID: 19444383777     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.300     Document Type: Article

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15. 3.
16. +|Fc) was performed with a carbon electrode.
17. -3 tetrabuthylammonium perchlorate was used. The test electrode was a glassy carbon disk electrode (3.0 mm diameter) and the reference electrode was Ag/AgCl. Fc was used as an internal reference.
18. w = 0.057) for 714 observed reflections. The elemental analysis was performed at Instrumental Analysis Center of Josai University. X-ray diffractions were measured on a Rigaku RAXIS-IV Imaging Plate diffractometer with graphite monochromated Mo Kα radiation. The crystallographic data in this manuscript have been deposited with Cambridge Crystallographic Data Centre as supplementary publication No. CCDC 258967-258970.