Facile synthesis of cross-conjugated gem-disubstituted trienes via palladium-catalyzed cross-coupling protocol of 1,1-disubstituted 2,4-diiodo-but-1-ene with alkenes

Synlett

Volumn , Issue 5, 2004, Pages 807-810

  Shi, Min ^a   Shao, Li Xiong ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

Alkenes; Cross conjugated trienes; Cross coupling reaction; Diiodides; Methylenecyclopropanes; Palladium catalyst

Indexed keywords

ALKENE DERIVATIVE; CYCLOPROPANE DERIVATIVE; IODINE; PALLADIUM;

ARTICLE; CATALYSIS; CONJUGATION; CROSS COUPLING REACTION; HECK REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; RING OPENING; SUBSTITUTION REACTION;

EID: 1942425209     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-820017     Document Type: Article

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31. 2: 519.9396; found: 519.9406.
32. 2: 290.1301; found: 290.1290.
33. 1H NMR as the corresponding coupling constant of the former is 16.5 Hz and 8.7 Hz for the latter (Supporting Information).