Influence of molecular dipole on monoacrylate monomer reactivity

Polymer

Volumn 46, Issue 13, 2005, Pages 4735-4742

  Kilambi, Harini ^a   Beckel, Eric R ^a   Berchtold, Kathryn A ^b   Stansbury, Jeffrey W ^c   Bowman, Christopher N ^a,c  

^a University of Colorado at Boulder   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF COLORADO   (United States)

Author keywords

Acrylate; Dipole moment; Polymerization kinetics

Indexed keywords

CORRELATION METHODS; POLYMERIZATION; REACTION KINETICS; SOLUTIONS; SOLVENTS; SYNTHESIS (CHEMICAL);

DIPOLE MOMENTS; MOLECULAR DIPOLES; MOLECULAR POLARITY; MONOMER REACTIVITY;

ACRYLIC MONOMERS;

POLYMER SCIENCE;

EID: 18844456556     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2005.04.006     Document Type: Article

References (26)

1. J.W. Finger, K.S. Lee, and W. Podszun Dent Mater 12 1996 256 261
2. Chen AC-P. Carbonate (alkyl) acrylate radiation-curable coating compositions, and method of curing. Mobil Oil Corporation, Patent# EP056526A1; July 28, 1982.
3. Hutchison JB, Haraldsson KT, Good TB, Sebra RP, Luo L, Anseth KS, et al. Robust polymer microfluidic device fabrication via contact liquid photolithographic polymerization (CLipp), Lab on a Chip. 2004;6:658.
4. C. Decker Nucl Instrum Method Phys Res B 151 1999 22 28
5. P. Bernhard, M. Hofmann, A. Schulthess, and B. Steinmann Chimia 48 1994 427 430
6. C. Decker, and B. Elzaouk J Appl Polym Sci 65 1997 833 844
7. C. Decker, and K. Moussa Die Makromol Chem 192 1991 507 522
8. C. Decker, and K. Moussa Eur Polym J 27 1991 403 411
9. C. Decker, and K. Moussa Eur Polym J 27 1991 881 889
10. K. Moussa, and C. Decker J Poly Sci, Part A: Polym Chem 31 1993 2197 2203
11. C. Decker, and K. Moussa Macromolecules 22 1989 4455 4462
12. C. Decker, and K. Moussa Makromol Chem, Rapid Commun 11 1990 159 167
13. E.R. Beckel, J. Nie, J.W. Stansbury, and C.N. Bowman Macromolecules 37 2004 4062 4069
14. K.A. Berchtold, J. Nie, J.W. Stansbury, B. Hacioglu, E.R. Beckel, and C.N. Bowman Macromolecules 37 2004 3165 3179
15. Bowman CN, Stansbury JW, Berchtold KA, Nie J. The Regents of the University of Colorado, USA. WO 2004/077511 A2, February 24, 2003, PCT Int Appl; 2004.
16. Berchtold KA. PhD thesis. University of Colorado; 2001.
17. C. Decker, and B. Elzaouk Eur Polym J 26 1990 393 401
18. Berchtold KA, Nie J, Elliot JE, Hacioglu B, Luo N, Trotter AJN, et al. Proc Radtech Europe; 2001. p. 265.
19. C. Decker, B. Elzaouk, and D. Decker J Macromol Sci-Pure Appl Chem A33 1996 173 190
20. T.Y. Lee, T.M. Roper, E.S. Jonsson, C.A. Guymon, and C.E. Hoyle Macromolecules 37 2004 3659 3665
21. J.F.G.A. Jansen, A.A. Dias, M. Dorschu, and B. Coussens Macromolecules 36 2003 3861 3873
22. J.F.G.A. Jansen, A.A. Dias, M. Dorschu, and B. Coussens Polym Prepr 42 2001
23. J.F.G.A. Jansen, A.A. Dias, M. Dorschu, and B. Coussens Macromolecules 35 2002 7529 7531
24. Jansen JFGA, Dias AA, Dorschu M, Coussens B. Radiation-curable compositions containing polar acrylates. PCT Int Appl, IPN WO 02/42383; 2002.
25. Berchtold KA, Nie J, Stansbury JW, Hacioglu B, Bowman CN. A study of the reactivity of monovinyl (meth)acrylates containing secondary functionalities: effect of spacer length. Submitted to Journal of Polymer Science. Part A, Polymer Chemistry.
26. K.A. Berchtold, B. Hacioglu, L.G. Lovell, J. Nie, and C.N. Bowman Macromolecules 34 2001 5103 5111