The utility of hypercoordination and secondary bonding for the synthesis of a binary organoelement oxo cluster

Dalton Transactions

Volumn , Issue 9, 2005, Pages 1563-1564

  Beckmann, Jens ^a,b   Dakternieks, Dainis ^a   Duthie, Andrew ^a   Mitchell, Cassandra ^a  

^a DEAKIN UNIVERSITY   (Australia)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BONDING; CARBON; CHEMICAL BONDS; MOLECULAR STRUCTURE; ORGANIC POLYMERS; SYNTHESIS (CHEMICAL); TELLURIUM; TIN;

BINARY ORGANOELEMENT; HYPERCOORDINATION; REACTANTS; SECONDARY BONDING;

ORGANOMETALLICS;

EID: 18844447257     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b502677f     Document Type: Article

References (13)

1. For recent reviews, see: V. Chandrasekhar, S. Nagendran and V. Baskar, Coord. Chem. Rev., 2002, 235, 1;
2. A. G. Davies, Organotin Chemistry, VCH, Weinheim, 2nd edn., 2004.
3. J. Beckmann, D. Dakternieks, J. O'Connell, K. Jurkschat and M. Schürmann, Eur. J. Inorg. Chem., 2002, 1484.
4. H. Puff, W. Schuh, R. Sievers, W. Wald and R. Zimmer, J. Organomet. Chem., 1984, 260, 271.
5. J. Beckmann, D. Dakternieks, A. Duthie, F. Ribot, M. Schürmann and N. A. Lewcenko, Organometallics, 2003, 22, 3257.
6. J. Beckmann, D. Dakternieks, A. Duthie, N. A. Lewcenko and C. Mitchell, Angew. Chem., Int. Ed., 2004, 43, 6683.
7. There is no clear boundary between secondary and hypervalent bonding. Both terms may indeed describe the same phenomenon. G. A. Landrum and R. Hoffmann, Angew. Chem., Int. Ed., 1998, 37, 1887.
8. (a) The tensor analyses were performed according to the method of Herzfeld and Bergen J. Herzfeld and X. Chen, in Encyclopedia of Nuclear Magnetic Resonance, ed. D. M. Grant and R. K. Harris, John Wiley & Sons, Chichester, 1996, vol. 7, p. 4362;
9. (b) Computer program used: DmFit 2002: D. Massiot, F. Fayon, M. Capron, I. King, S. Le Calvé, B. Alonso, J.-O. Durand, B. Bujoli, Z. Gan and G. Hoatson, Magn. Reson. Chem., 2002, 40, 70;
10. iso|;
11. 33 = -1639.
12. N. W. Alcock and W. D. Harrison, J. Chem. Soc., Dalton Trans., 1982, 709.
13. A. G. Davies, J. Chem. Res. (S), 2004, 309.