Parallel transformations of cyclohexene mediated by the Cp*W(NO) fragment

Journal of the American Chemical Society

Volumn 127, Issue 19, 2005, Pages 6928-6929

  Jin, Xing ^a   Legzdins, Peter ^a   Buschhaus, Miriam S A ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXENE DERIVATIVE; HYDROCARBON; MOLYBDENUM; ORGANOMETALLIC COMPOUND; TRANSITION ELEMENT; TUNGSTEN;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOGRAPHY; CRYSTALLIZATION; ELECTRON; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY DIFFRACTION;

EID: 18744386671     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0426692     Document Type: Article

References (14)

1. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley & Sons: New York, 2001; Chapter 14.
2. Activation and Functionalization of C-H Bonds; Goldberg, K. I., Goldman, A. S., Eds.; ACS Symposium Series 885; American Chemical Society: Washington, DC, 2004.
3. Pamplin, C. B.; Legzdins, P. Acc. Chem. Res. 2003, 36, 223.
4. 2 complexes has been presented previously. See: Szymańska- Buzar, T.; Jaroszewski, M.; Wilgocki, M.; Ziółkowski, J. J. J. Mol. Catal. A: Chem. 1996, 112, 203.
5. The insertion of coordinated alkenes into M-H bonds is a fundamental transformation in transition-metal organometallic chemistry; see ref 1.
6. 2 fashion. See: Debad, J. D.; Legzdins, P.; Young, M. A.; Batchelor, R. J.; Einstein, F. W. B. J. Am. Chem. Soc. 1993, 115, 2051.
7. Complete experimental details are provided in the Supporting Information.
8. Ng, S. H. K.; Adams, C. S.; Hayton, T. W.; Legzdins, P.; Patrick, B. O. J. Am. Chem. Soc. 2003, 125, 15210.
9. 2) = 1.138 for 8657 reflections and 402 variables.
10. Legzdins, P.; Martin, J. T.; Einstein, F. W. B.; Willis, A. C. J. Am. Chem. Soc. 1986, 108, 7971 and references therein.
11. 2) = 1.068 for 4813 reflections and 231 variables.
12. (a) Hunter, A. D.; Legzdins, P.; Einstein, F. W. B.; Willis, A. C.; Bursten, B. E.; Gatter, M. G. J. Am. Chem. Soc. 1986, 108, 3843.
13. (b) Christensen, N. J.; Hunter, A. D.; Legzdins, P. Organometallics 1989, 8, 930.
14. Wada, K. Kyoto University, Kyoto, Japan. Personal communication, 2005.