Picosecond Relaxation of 3MLCT Excited States of [Re(Etpy)(Co)3(dmb)]+ and [Re(Cl)(Co)3(bpy)] as Revealed by Time-Resolved Resonance Raman, UV - vis, and IR Absorption Spectroscopy

Journal of Physical Chemistry A

Volumn 108, Issue 13, 2004, Pages 2363-2369

  Liard, Davina J ^a   Busby, Michael ^a   Matousek, Pavel ^b   Towrie, Michael ^b   Vlček Jr , Antonín ^a  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

^b Harwell Science and Innovation Campus   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ABSORPTION SPECTROSCOPY; COMPLEXATION; COOLING; ELECTRONS; GROUND STATE; INFRARED SPECTROSCOPY; PHOTONS; RAMAN SPECTROSCOPY; RESONANCE; ULTRAVIOLET SPECTROSCOPY;

EXCITED STATES; PICOSECOND RELAXATION;

RHENIUM COMPOUNDS;

EID: 1842814106     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0366320     Document Type: Article

References (75)

1. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
2. Geoffroy, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
3. Stufkens, D. J. Comments Inorg. Chem. 1992, 13, 359.
4. Vlček, A., Jr. In Electron Transfer in Chemistry; Balzani, V., Astruc, D., Eds.; Wiley-VCH: Weinheim, 2001; Vol. 2, p 804.
5. Tachibana, Y.; Moser, J. E.; Grätzel, M.; Klug, D. R.; Durrant, J. R. J. Phys. Chem. 1996, 100, 20056.
6. Benkö, G.; Kallioinen, J.; Korppi-Tommola, J. E. I.; Yartsev, A. P.; Sundström, V. J. Am. Chem. Soc. 2002, 124, 489.
7. Kallioinen, J.; Benkö, G.; Sundström, V.; Korppi-Tommola, J. E. I.; Yartsev, A. P. J. Phys. Phem. B 2002, 106, 4396.
8. Asbury, J. B.; Ellingson, R. J.; Ghosh, H. N.; Ferrere, S.; Nozik, A. J.; Lian, T. J. Phys. Chem. B 1999, 103, 3110.
9. Ellingson, R. J.; Asbury, J. B.; Ferrere, S.; Ghosh, H. N.; Sprague, J. R.; Lian, T.; Nozik, A. J. J. Phys. Chem. B 1998, 102, 6455.
10. Asbury, J. B.; Hao, E.; Wang, Y.; Ghosh, H. N.; Lian, T. J. Phys. Chem. B 2001, 105, 4545.
11. Wang, Y.; Asbury, J. B.; Lian, T. J. Phys. Chem. A 2000, 104, 4291.
12. Chen, P.; Mecklenburg, S. L.; Meyer, T. J. J. Phys. Chem. 1993, 97, 13126.
13. Liard, D. J.; Vlček, A., Jr. Inorg. Chem. 2000, 39, 485.
14. Liard, D. J.; Busby, M.; Farrell, I. R.; Matousek, P.; Towrie, M.; Vlček, A., Jr. J. Phys. Chem. A 2004, 108, 556.
15. Wang, Y.; Hauser, B. T.; Rooney, M. M.; Burton, R. D.; Schanze, K. S. J. Am. Chem. Soc. 1993, 115, 5675.
16. Chen, P.; Westmoreland, T. D.; Danielson, E.; Schanze, K. S.; Anthon, D.; Neveux, P. E., Jr.; Meyer, T. J. Inorg. Chem. 1987, 26, 1116.
17. Chen, P.; Duesing, R.; Graff, D. K.; Meyer, T. J. J. Phys. Chem. 1991, 95, 5850.
18. Trammell, S.; Goodson, P. A.; Sullivan, B. P. Inorg. Chem. 1996, 35, 1421.
19. Chen, P.; Danielson, E.; Meyer, T. J. J. Phys. Chem. 1988, 92, 3708.
20. Schoonover, J. R.; Chen, P.; Bates, W. D.; Dyer, R. B.; Meyer, T. J. Inorg. Chem. 1994, 33, 793.
21. Schoonover, J. R.; Strouse, G. F.; Chen, P.; Bates, W. D.; Meyer, T. J. Inorg. Chem. 1993, 32, 2618.
22. Cabana, L. A.; Schanze, K. S. Adv. Chem. Ser. 1990, 226, 101.
23. Lucia, L. A.; Wang, Y.; Nafisi, K.; Netzel, T. L.; Schanze, K. S. J. Phys. Chem. 1995, 99, 11801.
24. Wang, Y.; Lucia, L. A.; Schanze, K. S. J. Phys. Chem. 1995, 99, 1961.
25. Wang, Y.; Schanze, K. S. J. Phys. Chem. 1996, 100, 5408.
26. Damrauer, N. H.; Cerullo, G.; Yeh, A.; Boussie, T. R.; Shank, C. V.; McCusker, J. K. Science 1997, 275, 54.
27. Yeh, A. T.; Shank, C. V.; McCusker, J. K. Science 2000, 289, 935.
28. Bhasikuttan, A. C.; Suzuki, M.; Nakashima, S.; Okada, T. J. Am. Chem. Soc. 2002, 124, 8398.
29. Damrauer, N. H.; McCusker, J. K. J. Phys. Chem. A 1999, 103, 8440.
30. Huber, R.; Moser, J.-E.; Grätzel, M.; Wachtveitl, J. J. Phys. Chem. B 2002, 106, 6494.
31. Önfelt, B.; Lincoln, P.; Nordén, B.; Baskin, J. S.; Zewail, A. H. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 5708.
32. Shaw, G. B.; Brown, C. L.; Papanikolas, J. M. J. Phys. Chem. A 2002, 106, 1483.
33. Asbury, J. B.; Wang, Y.; Lian, T. Bull. Chem. Soc. Jpn. 2002, 75, 973.
34. Worl, L. A.; Duesing, R.; Chen, P.; Della Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 849.
35. Stufkens, D. J.; Vlček, A., Jr. Coord. Chem. Rev. 1998, 177, 127.
36. Wrighton, M. S.; Morse, D. L. J. Am. Chem. Soc. 1974, 96, 998.
37. Luong, J. C.; Nadjo, L.; Wrighton, M. S. J. Am. Chem. Soc. 1978, 100, 5790.
38. Kalyanasundaram, K. J. Chem. Soc., Faraday Trans. 2 1986, 82, 2401.
39. Busby, M.; Liard, D. J.; Motevalli, M.; Toms, H.; Vlček, A., Jr. Inorg. Chim. Acta 2004, 357, 167.
40. Staal, L. H.; Oskam, A.; Vrieze, K. J. Organomet. Chem. 1979, 170, 235.
41. Vlček, A., Jr.; Farrell, I. R.; Liard, D. J.; Matousek, P.; Towrie, M.; Parker, A. W.; Grills, D. C.; George, M. W. J. Chem. Soc., Dalton Trans. 2002, 701.
42. Matousek, P.; Parker, A. W.; Taday, P. F.; Toner, W. T.; Towrie, M. Opt. Comm. 1996, 127, 307.
43. Towrie, M.; Parker, A. W.; Shaikh, W.; Matousek, P. Meas. Sci. Technol. 1998, 9, 816.
44. Matousek, P.; Towrie, M.; Stanley, A.; Parker, A. W. Appl. Spectrosc. 1999, 53, 1485.
45. Matousek, P.; Towrie, M.; Ma, C.; Kwok, W. M.; Phillips, D.; Toner, W. T.; Parker, A. W. J. Raman Spectrosc. 2001, 32, 983.
46. Towrie, M.; Grills, D. C.; Dyer, J.; Weinstein, J. A.; Matousek, P.; Barton, R.; Bailey, P. D.; Subramaniam, N.; Kwok, W. M.; Ma, C. S.; Phillips, D.; Parker, A. W.; George, M. W. Appl. Spectrosc. 2003, 57, 367.
47. Vergeer, F. W.; Kleverlaan, C. J.; Stufkens, D. J. Inorg. Chim. Acta 2002, 327, 126.
48. Treffert-Ziemelis, S. M.; Golus, J.; Strommen, D. P.; Kincaid, J. R. Inorg. Chem. 1993, 32, 3890.
49. Vlček, A. J. Coord. Chem. Rev. 2002, 230, 225.
50. Smothers, W. K.; Wrighton, M. S. J. Am. Chem. Soc. 1983, 105, 1067.
51. Mallick, P. K.; Strommen, D. P.; Kincaid, J. R. J. Am. Chem. Soc. 1990, 112, 1686.
52. Mallick, P. K.; Danzer, G. D.; Strommen, D. P.; Kincaid, J. R. J. Phys. Chem. 1988, 92, 5628.
53. Zális̀, S.; Farrell, I. R.; Vlček, A., Jr. J. Am. Chem. Soc. 2003, 125, 4580.
54. Claude, J. P.; Omberg, K. M.; Williams, D. S.; Meyer, T. J. J. Phys. Chem. A 2002, 106, 7795.
55. Dattelbaum, D. M.; Omberg, K. M.; Schoonover, J. R.; Martin, R. L.; Meyer, T. J. Inorg. Chem. 2002, 41, 6071.
56. Gamelin, D. R.; George, M. W.; Glyn, P.; Grevels, F.-W.; Johnson, F. P. A.; Klotzbucher, W.; Morrison, S. L.; Russell, G.; Schaffner, K.; Turner, J. J. Inorg. Chem. 1994, 33, 3246.
57. George, M. W.; Johnson, F. P. A.; Westwell, J. R.; Hodges, P. M.; Turner, J. J. J. Chem. Soc., Dalton Trans. 1993, 2977.
58. Turner, J. J. Coord. Chem. Rev. 2002, 230, 212.
59. -1 bleach is caused by narrowing and upward shift of the A″ band, which seems to occur initially at much lower wavenumbers than indicated by the Lorentzian analysis.
60. Rosenthal, S. J.; Xie, X.; Du, M.; Fleming, G. R. J. Chem. Phys. 1991, 95, 4715.
61. Woodruff, W. H.; Dallinger, R. F. J. Am. Chem. Soc. 1979, 101, 4391.
62. Forster, M.; Hester, R. E. Chem. Phys. Lett. 1981, 81, 42.
63. Noble, B. C.; Peacock, R. D. Spectrochim. Acta 1990, 46A, 407.
64. Braterman, P. S.; Song, J.-I. J. Org. Chem. 1991, 56, 4678.
65. König, E.; Kremer, S. Chem. Phys. Lett. 1970, 5, 87.
66. Krejčik, M.; Vlček, A. A. J. Electroanal. Chem. 1991, 313, 243.
67. Nakabayashi, T.; Kamo, S.; Sakuragi, H.; Nishi, N. J. Phys. Chem. A 2001, 105, 8605.
68. Leonard, J. D., Jr.; Gustafson, T. L. J. Phys. Chem. A 2001, 105, 1724.
69. Hamaguchi, H.; Iwata, K. Bull. Chem. Soc. Jpn. 2002, 75, 883.
70. Iwata, K.; Hamaguchi, H. J. Phys. Chem. A 1997, 101, 632.
71. Werncke, W.; Wachsmann-Hogiu, S.; Dreyer, J.; Vodchits, A. I.; Elsaesser, T. Bull. Chem. Soc. Jpn. 2002, 75, 1049.
72. Scholes, G. D.; Matousek, P.; Parker, A. W.; Phillips, D.; Towrie, M. J. Phys. Chem. A 1998, 102, 1431.
73. Lian, T.; Bromberg, S. E.; Asplund, M. C.; Yang, H.; Harris, C. B. J. Phys. Chem. 1996, 100, 11994.
74. 3MLCT state or time-dependent reabsorption of the Raman-scattered light can be excluded on the following grounds: (i) The increase of UV - vis excited-state absorption occurs only at certain wavelengths whereas a uniform increase is expected to manifest population dynamics, Integrated areas of excited-state IR bands are time-independent, (ii) Raman scattering occurs in the plateau of the transient absorption spectrum, between 410 and 430 nm, where the absorbance hardly changes with time, Figure 6.
75. Zális̀, S.; Busby, M.; Kotrba, T.; Matousek, P.; Towrie, M.; Vlček, A., Jr. Inorg. Chem. 2004 43, 1723.