Kinetics on the hydrolysis of fatty acid esters in subcritical water

Chemical Engineering Journal

Volumn 99, Issue 1, 2004, Pages 1-4

  Khuwijitjaru, Pramote ^a   Fujii, Tomoyuki ^a   Adachi, Shuji ^a   Kimura, Yukitaka ^a   Matsuno, Ryuichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Esters; Fatty acids; Hydrolysis; Kinetics; Subcritical water

Indexed keywords

ACTIVATION ENERGY; ENTHALPY; HYDROLYSIS; RATE CONSTANTS; REACTION KINETICS; THERMAL EFFECTS; WATER;

BATCH REACTOR; HOMOGENEOUS REACTION;

FATTY ACIDS;

FATTY ACID;

ARRHENIUS;

EID: 1842640107     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2003.08.002     Document Type: Article

References (15)

1. Holgate H.R.Meyer J.C.Tester J.W.Glucose hydrolysis and oxidation in supercritical water AIChE J. 41 1995 637-647
2. Kabyemela B.M.Adschiri T.Malaluan R.M.Arai K.Kinetics of glucose epimerization and decomposition in subcritical and supercritical water Ind. Eng. Chem. Res. 36 1997 1552-1558
3. Kabyemela B.M.Takigawa M.Adschiri T.Malaluan R.M.Arai K.Mechanism and kinetics of cellobiose decomposition in sub- and supercritical water Ind. Eng. Chem. Res. 37 1998 357-361
4. Yoshida H.Terashima M.Takahashi Y.Production of organic acids and amino acids from fish meat by subcritical water hydrolysis Biotechnol. Prog. 15 1999 1090-1094
5. Sato N.Daimon H.Fujie K.Decomposition of glycine in high temperature and high pressure water (in Japanese) Kagaku Kogaku Ronbunshu 28 2002 113-117
6. Patil T.A.Butala D.N.Raghunathan T.S.Shankar H.S.Thermal hydrolysis of vegetable oils and fats. 1. Reaction kinetics Ind. Eng. Chem. Res. 27 1988 727-735
7. P. Møller, A method for splitting of fats and other esters by hydrolysis, DK Patent WO 97/07187, 1997.
8. Holliday R.L.King J.W.List G.R.Hydrolysis of vegetable oils in sub- and supercritical water Ind. Eng. Chem. Res. 36 1997 932-935
9. Krop H.B.van Velzen M.J.M.Parsons J.R.Govers H.A.J.n-Octanol-water partition coefficients, aqueous solubilities and Henry's law constants of fatty acid esters Chemosphere 34 1997 107-109
10. Khuwijitjaru P.Adachi S.Matsuno R.Solubility of fatty acids in water at elevated temperatures Biosci. Biotechnol. Biochem. 66 2002 1723-1726
11. Wagner W.Pruß A.The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use J. Phys. Chem. Ref. Data 31 2002 387-535
12. Taylor J.D.Steinfeld J.I.Lesutis H.P.Tester J.W.Experimental measurement of the rate of methyl tert-butyl ether hydrolysis in sub- and supercritical water Ind. Eng. Chem. Res. 40 2001 67-74
13. Krammer P.Vogel H.Hydrolysis of esters in subcritical and supercritical water J. Supercrit. Fluids 16 2000 189-206
14. H.P. Lesutis, R. Gläser, C.L. Liotta, C.A. Eckert, Acid/base-catalyzed ester hydrolysis in near-critical water, Chem. Commun. (1999) 2063-2064.
15. Bröll D.Kaul C.Krämer A.Krammer P.Richter T.Jung M.Vogel H.Zehner P.Chemistry in supercritical water Angew. Chem. Int. Ed. 38 1999 2998-3014