Mechanism and Kinetics of Cellobiose Decomposition in Sub- and Supercritical Water

Industrial and Engineering Chemistry Research

Volumn 37, Issue 2, 1998, Pages 357-361

  Kabyemela, B M ^a   Takigawa, M ^a   Adschiri, T ^a   Malaluan, R M ^a   Arai, K ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ALDEHYDES; CHEMICAL BONDS; DECOMPOSITION; GLUCOSE; HYDROLYSIS; PYROLYSIS; REACTION KINETICS; WATER;

CELLOBIOSE; SUPERCRITICAL WATER;

CELLULOSE;

EID: 0031996642     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9704408     Document Type: Article

References (13)

1. Adschiri, T.; Hirose, S.; Malaluan, R.; Arai, K. Noncatalytic Conversion of Cellulose in Supercritical and Subcritical Water. J. Chem. Eng. Jpn. 1993, 26, 676.
2. Amis, E. S.; Hinton, J. F. Solvent Effects on Chemical Phenomena; Academic Press: New York, 1973.
3. Bobleter, O.; Bonn, G. Hydrothermolysis of Cellobiose and Its Reaction Product D-Glucose. Carbohydr. Res. 1983, 124, 185.
4. Bunow, B., Knott, G., Eds.; A Mathematical Modelling Laboratory - MLAB Reference Manual; Civilized Software Inc.: Bethesda, MD, 1995.
5. Fengel, D., Wegener G., Eds. Wood: Chemistry, Ultrastructure, Reactions; Walter de Gruyter: New York, 1989.
6. Kabyemela, B. M.; Adschiri, T.; Malaluan, R. M.; Arai, K. Kinetics of Glucose Epimerization and Decomposition in Subcritical and Supercritical Water. Ind. Eng. Chem. Res. 1997a, 36, 1552.
7. Kabyemela, B. M.; Adschiri, T.; Malaluan, R. M.; Arai, K. Degradation Kinetics of Dihydroxyacetone and Glyceraldehyde in Sub- and Supercritical Water. Ind. Eng. Chem. Res. 1997b, 36, 2025.
8. Knott, G., Ed. A Mathematical Modelling Laboratory - MLAB Application Manual; Civilized Software Inc.: Bethesda, MD, 1995.
9. Koll, P.; Borchers, G.; Metzger, J. O. Preparative Isolation of Oligomers with a Terminal Anhydrosugar Unit by Thermal Degradation of Chitin and Cellulose. J. Anal. Appl. Pyrolysis 1990, 17, 319.
10. Malaluan, R. M. A Study of Cellulose Decomposition in Subcritical and Supercritical Water. Ph.D. Dissertation, Tohoku University, Sendai, 1995.
11. Ponder G. R.; Richards G. N. Pyrolysis of Inulin, Glucose and Fructose. Carbohydr. Res. 1993, 244, 341.
12. Sasaki, M.; Kabyemela, B.; Adschiri, T.; Malaluan, R.; Hirose, S.; Takeda, N.; Arai, K. Cellulose Hydrolysis in Supercritical Water. Proceedings of the 4th International Symposium on Supercritical Fluids; Tohuku University Press: Sendai, Japan, 1997; Vol. B, p 583.
13. Uhl, V. W.; Gray, J. B. Mixing: Theory and Practice; Academic Press Inc.: New York, 1986; Vol. 3.