Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole

Journal of Macromolecular Science - Pure and Applied Chemistry

Volumn 41, Issue 4, 2004, Pages 401-418

  Yilmaz, F ^a   Sel, O ^b   Guner, Y ^b   Toppare, L ^b   Hepuzer, Y ^a   Yagci, Y ^a  

^a ISTANBUL TECHNICAL UNIVERSITY   (Turkey)

^b MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

1,1 Diphenylethene; Conducting copolymers; Electrochemical grafting; Poly(methylmethacrylate b 3 methylthienylmethacrylate)

Indexed keywords

COPOLYMERIZATION; ELECTROCHROMIC DEVICES; ELECTROLYSIS; GRAFT COPOLYMERS; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; POLYMERIC MEMBRANES; SECONDARY BATTERIES; SYNTHESIS (CHEMICAL); TENSILE STRENGTH;

1,1-DIPHENYLETHENE; CONDUCTING COPOLYMERS; ELECTROCHEMICAL GRAFTING; POLY(METHYLMETHACRYLATE-B-3-METHYLTHIENYLMETHACRYLATE);

BLOCK COPOLYMERS;

EID: 1842584767     PISSN: 10601325     EISSN: None     Source Type: Journal    
DOI: 10.1081/MA-120028475     Document Type: Article

References (25)

1. Bittihn, R.; Ely, G.; Woeffler, F.; Munstedt, H.; Narmann, H.; Naegele, D. Polypyrrole as an electrode material for secondary lithium cells. Makromol. Chem. Makromol. Symp. 1987, 8, 51-59.
2. Mermilliod, N.; Tanguy, J.; Petiot, F. A study of chemically synthesized polypyrrole as electrode materials for material for battery applications. J. Electrochem. Soc. 1986, 133, 1073-1079.
3. Martin, C.R.; Liang, W.; Menon, V.; Parthasarathy, R.; Parthasarathy, A. Electronically conductive polymers as chemically-selective layers for membrane-based separations. Synth. Met. 1993, 57, 3766-3773.
4. Gustafsson, J.C.; Inganas, O.; Anderson, A.M. Conductive polyheterocycles as electrode materials in solid state electrochromic devices. Synth. Met. 1994, 62, 17-21.
5. DePaoli, M.; Panero, S.; Passerini, S.; Scrosatti, B. Polypyrrole-dodecyl-sulfate 2 × 104 cycles with an organic electrochromic material in a basic-medium. Adv. Mater. 1990, 2, 480-482.
6. Schwendeman, I.; Hickman, R.; Sonmez, G.; Schottland, P.; Zong, K.; Welsh, D.M.; Reynolds, J.R. Enhanced contrast dual polymer electrochromic devices. Chem. Mater. 2002, 14, 3118-3122.
7. Park, Y.H.; Park, S.B. Preparation and electroactivity of poly(methylmethacrylate-co-pyrrolylmethylstyrene)-g-polypyrrole. Synth. Met. 2002, 128, 229-234.
8. DePaoli, M.; Waltman, J.; Diaz, A.; Bargon, J. An electrically conductive plastic composite derived from polypyrrole and polyvinyl-chloride. Polym. Sci. Polym. Chem. Ed. 1985, 23, 1687-1698.
9. Wang, H.; Toppare, L.; Fernandez, E. Conducting polymer blends polythiophene and polypyrrole blends with polystyrene and poly(ewphenol-a carbonate). Macromolecules 1990, 23, 1053-1059.
10. Solomon, D.H.; Rizzardo, P.; Cacioli, P. Free radical Polymerization and the produced polymers. Chem. Abstr. 1985, 221335q.
11. Georges, M.K.; Veregin, R.P.N.; Kazmaier, P.M.; Hamer, G.K. Mechanism of living free-radical polymerizations with narrow polydispersity-electron-spin- resonance and kinetic-studies. Macromolecules 1995, 28, 4391-4398.
12. Georges, M.K.; Veregin, R.P.N.; Kazmaier, P.M.; Hamer, G.K. Narrow molecular-weight resins by a free-radical polymerization process. Macromolecules 1993, 26, 2987-2988.
13. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Polymerization of methylmethacrylate with the carbon-tetrachloride dichlorotris (triphenylphosphine)ruthenium(ii) methylaluminum bis(2,6-di-tert-butylphenoxide) initiating sytem - possibility of living radical polymerization. Macromolecules 1995, 28, 1721-1723.
14. Wang, J.S.; Matyjaszewski, K. Controlled living radical polymerization - halogen atom-transfer radical polymerization promoted by a Cu(I)Cu(II) redox process. Macromolecules 1995, 28, 7901-7910.
15. Wang, J.S.; Matyjaszewski, K. Controlled living radical polymerization - atom-transfer radical polymerization in the presence of transition-metal complexes. J. Am. Chem. Soc. 1995, 117, 5614-5615.
16. Mayadunne, R.T.A.; Rizzardo, E.; Chiefari, J.; Chong, Y.K.; Moad, G.; Thang, S.H. Living radical polymerization with reversible addition-fragmentation chain transfer (graft polymerization) using dithiocarbamates as chain transfer agents. Macromolecules 1999, 32, 6977-6980.
17. Chong, Y.K.; Le, T.P.T.; Moad, G.; Rizzardo, E.; Thang, S.H. A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: the raft process. Macromolecules 1999, 32, 2071-2074.
18. Hawthorne, D.G.; Moad, G.; Rizzardo, E.; Thang, S.H. Living radical polymerization with reversible addition-fragmentation chain transfer (graft): direct esr observation of intermediate radicals. Macromolecules 1999, 32, 5457-5459.
19. Wieland, P.C.; Raether, B.; Nuyken, O. A new additive for controlled radical polymerization. Macromol. Rapid. Commun. 2001, 22, 700-703.
20. Cirpan, A.; Alkan, S.; Toppare, L.; Hepuzer, Y.; Yagci, Y. Conducting graft copolymers of poly(3-methyl thienyl methacrylate) with pyrrole and thiophene. J. Polym. Sci. Part A: Polym. Chem. 2002, 40, 4131-4140.
21. Guner, Y.; Toppare, L.; Hepuzer, Y.; Yagci, Y. Conducting copolymers of random copolymers of methyl methacrylate and 3-methylthienyl methacrylate with pyrrole and thiophene. Eur. Polym. J., submitted.
22. Braun, D.; Bledzki, A. Initiation of polymerization with substituted ethanes 8. Polymerization of styrene. Macromol. Chem. 1986, 187, 2599-2608.
23. Braun, D.; Linder, H.J.; Tretner, H. Initiation of polymerization with substituted ethanes 12. Free-radical polymerization of methyl-methacrylate and styrene initiated with 3-methoxycarbonyl-3-methyl-2,2,5,5- tetraphenylhexanedinitrile. Eur. Polym. J. 1989, 25, 725-730.
24. Biran, C.; Toppare, L.; Tincer, T.; Yagci, Y.; Harabagiu, V. Mechanical properties of conducting H-type polysiloxane-polypyrrole graft copolymers and polytetrahydrofuran-polypyrrole block copolymers. J. App. Polym. Sci. 2002, 86, 1663.
25. Biran, C.; Toppare, L.; Tincer, T.; Yagci, Y.; Harabagiu, V. The effect of long term ambient aging on the mechanical properties of conducting polysiloxane-polypyrrole graft copolymers. Chem. Eng. Commun. 2003, 190, 823-830.