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The minimized structure of multichromophore 30 was obtained by applying the MM+ force field and the Conjugate Gradient algorithm implemented in the HyperChem 6.0 program package. The hypersurface of the TDI core molecule was first calculated separately by using the semiempirical PM3 method, and a global minimum was evaluated. In the next step, the separately minimized dendrimer branches were attached to the core, and the geometry of the complete molecule was calculated with the MM+ force field and the Fletcher Reeves algorithm. Due to the fairly flat hypersurface generally obtained for higher generation dendrimers, the three-dimensional structure of 30 represents one of several possible local minima. However, this structure was found to be sufficient to evaluate the dimensions of the molecules as well as the approximate position of the chromophores with respect to each other.
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