Copper catalyzed oxidation of sulfides to sulfoxides with aqueous hydrogen peroxide

Tetrahedron Letters

Volumn 46, Issue 22, 2005, Pages 3819-3822

  Velusamy, Subbarayan ^a   Kumar, Akkilagunta V ^a   Saini, Rakesh ^a   Punniyamurthy, T ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY GUWAHATI   (India)

Author keywords

CuSalenH4; Hydrogen peroxide; Oxidation; Sulfide; TEMPO

Indexed keywords

COPPER; HYDROGEN PEROXIDE; SULFIDE; SULFOXIDE;

ADDITION REACTION; AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; OXIDATION KINETICS; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 18144395052     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.03.194     Document Type: Article

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39. 4) and concentrated under reduced pressure to yield a residue which was passed through a short pad of silica gel using ethyl acetate and hexane as eluent to provide analytically pure sulfoxide. Evaporation of the aqueous layer provided the copper(II) complex which could be recycled without loss of activity