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0141602023
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note
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In the absence of catalyst, conversions to sulfoxides 2a, 2b, and 2d were in the range 53-76% after 24 h in the presence of 5 equiv of 60% hydrogen peroxide. Sulfoxide 2c was formed in a yield >98% after 20 h (see Supporting Information for details of uncatalyzed reactions).
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17
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0141602022
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note
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8 Under carefully controlled conditions (stoichiometric hydrogen peroxide, 0°C) sulfones were observed in the reaction mixture (3-14%) together with the expected sulfoxides. Compound 2a was obtained together with 14% of sulfone 3a.
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18
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0032580407
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