Synthesis and characterization of 17-valence-electron [CpCr(NO)X2]- anions: Oxidatively induced loss of the nitrosyl ligand

Journal of the American Chemical Society

Volumn 119, Issue 15, 1997, Pages 3513-3522

  Legzdins, Peter ^a   Stephen McNeil, W ^a   Rettig, Steven J ^a   Smith, Kevin M ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; METAL COMPLEX;

ARTICLE; COMPLEX FORMATION; CRYSTALLOGRAPHY; ELECTRON SPIN RESONANCE; IN VITRO STUDY; REACTION ANALYSIS;

EID: 16944362154     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963464z     Document Type: Article

References (137)

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10. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
11. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
12. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
13. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
14. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
15. M = Mo: (a) Poli, R.; Krueger, S. T.; Abugideiri, F.; Haggerty, B. S.; Rheingold, A. L. Organometallics 1991, 10, 3041. (b) Poli, R.; Owens, B. E.; Linck, R. G. J. Am. Chem. Soc. 1992, 114, 1302. (c) Abugideiri, F.; Keogh, D. W.; Poli, R. J. Chem. Soc., Chem. Commun. 1994, 2317. (d) Cole, A. A.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chim. Acta 1995, 240, 355. (e) Fettinger, J. C.; Keogh, D. W.; Poli, R. J. Am. Chem. Soc. 1996, 118, 3617. (f) Abugideiri, F.; Fettinger, J. C.; Keogh, D. W.; Poli, R. Organometallics 1996, 15, 4407.
16. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
17. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
18. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
19. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
20. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
21. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
22. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
23. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
24. M = Cr: (a) Grohmann, A.; Köhler, F. H.; Müller, G.; Zeh, H. Chem. Ber. 1989, 722, 897. (b) Theopold, K. H. Acc. Chem. Res. 1990, 23, 263. (c) Thomas, B. J.; Noh, S.-K.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893. (d) Bhandari, G.; Kim, Y.; McFarland, J. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1995, 14, 738. (e) Bhandari, G.; Rheingold, A. L.; Theopold, K. H. Chem. Eur. J. 1995, 1, 199. (f) Fettinger, J. C.; Mattamana, S. P.; Poli, R.; Rogers, R. D. Organometallics 1996, 15, 4211. (g) Jolly, P. W. Acc. Chem. Res. 1996, 29, 544. (h) Liang, Y.; Yap, G. P. A.; Rheingold, A.; Theopold, K. H. Organometallics 1996, 75, 5284. (i) White, P. A.; Calabrese, J.; Theopold, K. H. Organometallics 1996, 15, 5471.
25. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
26. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
27. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
28. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
29. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
30. M = V: (a) Nieman, J.; Teuben, J. H.; Huffman, J. C.; Caulton, K. G. J. Organomet. Chem. 1983, 255, 193. (b) Nieman, J.; Pattiasina, J. W.; Teuben, J. H. J. Organomet. Chem. 1984, 262, 157. (c) Nieman, J.; Teuben, J. H. Organometallics 1986, 5, 1149. (d) Hessen, B.; Lemmen, T. H.; Luttikhedde, H. J. G.; Teuben, J. H.; Petersen, J. L.; Huffman, J. C.; Jagner, S.; Caulton, K. G. Organometallics 1987, 6, 2354. (e) Hessen, B.; Buijink, J.-K. F.; Meetsma, A.; Teuben, J. H.; Helgesson, G.; Håkansson, M.; Jagner, S.; Spek, A. L. Organometallics 1993, 12, 2268. (f) Buijink, J.-K. F.; Kloetstra, K. R.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1996, 15, 2523.
31. M = Nb: (a) Siemeling, U.; Gibson, V. C. J. Organomet. Chem. 1992, 424, 159. (b) de la Mata, J.; Galakhov, M. V.; Gómez, M.; Royo, P. Organometallics 1993, 12, 1189. (c) Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chem. 1995, 34, 2343. (d) Fettinger, J. C.; Keogh, D. W.; Kraatz, H.-B.; Poli, R. Organometallics 1996, 15, 5489.
32. M = Nb: (a) Siemeling, U.; Gibson, V. C. J. Organomet. Chem. 1992, 424, 159. (b) de la Mata, J.; Galakhov, M. V.; Gómez, M.; Royo, P. Organometallics 1993, 12, 1189. (c) Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chem. 1995, 34, 2343. (d) Fettinger, J. C.; Keogh, D. W.; Kraatz, H.-B.; Poli, R. Organometallics 1996, 15, 5489.
33. M = Nb: (a) Siemeling, U.; Gibson, V. C. J. Organomet. Chem. 1992, 424, 159. (b) de la Mata, J.; Galakhov, M. V.; Gómez, M.; Royo, P. Organometallics 1993, 12, 1189. (c) Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chem. 1995, 34, 2343. (d) Fettinger, J. C.; Keogh, D. W.; Kraatz, H.-B.; Poli, R. Organometallics 1996, 15, 5489.
34. M = Nb: (a) Siemeling, U.; Gibson, V. C. J. Organomet. Chem. 1992, 424, 159. (b) de la Mata, J.; Galakhov, M. V.; Gómez, M.; Royo, P. Organometallics 1993, 12, 1189. (c) Fettinger, J. C.; Keogh, D. W.; Poli, R. Inorg. Chem. 1995, 34, 2343. (d) Fettinger, J. C.; Keogh, D. W.; Kraatz, H.-B.; Poli, R. Organometallics 1996, 15, 5489.
35. M = W: (a) Liu, A. H.; Murray, R. C.; Dewan, J. C.; Santarsiero, B. D.; Schrock, R. R. J. Am. Chem. Soc. 1987, 709, 4282. (b) O'Regan, M. B.; Liu, A. H.; Finch, W. C.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1990, 112, 4331. (c) Schrock, R. R.; Glassman, T. E.; Vale, M. G.; Kol, M. J. Am. Chem. Soc. 1993, 115, 1760.
36. M = W: (a) Liu, A. H.; Murray, R. C.; Dewan, J. C.; Santarsiero, B. D.; Schrock, R. R. J. Am. Chem. Soc. 1987, 709, 4282. (b) O'Regan, M. B.; Liu, A. H.; Finch, W. C.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1990, 112, 4331. (c) Schrock, R. R.; Glassman, T. E.; Vale, M. G.; Kol, M. J. Am. Chem. Soc. 1993, 115, 1760.
37. M = W: (a) Liu, A. H.; Murray, R. C.; Dewan, J. C.; Santarsiero, B. D.; Schrock, R. R. J. Am. Chem. Soc. 1987, 709, 4282. (b) O'Regan, M. B.; Liu, A. H.; Finch, W. C.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1990, 112, 4331. (c) Schrock, R. R.; Glassman, T. E.; Vale, M. G.; Kol, M. J. Am. Chem. Soc. 1993, 115, 1760.
38. M = Fe: (a) Roger, C.; Hamon, P.; Toupet, L.; Rabaâ, H.; Saillard, J.-Y.; Hamon, J.-R.; Lapinte, C. Organometallics 1991, 10, 1045. (b) Tenorio, J. M.; Puerta, M. C.; Valerga, P. Organometallics 1994, 13, 3330. (c) Leal, A. J.; Tenorio, J. M.; Puerta, M. C.; Valerga, P. Organometallics 1995, 14, 3839. (d) Hamon, P.; Toupet, L.; Hamon, J.-R.; Lapinte, C. Organometallics 1996, 15, 10.
39. M = Fe: (a) Roger, C.; Hamon, P.; Toupet, L.; Rabaâ, H.; Saillard, J.-Y.; Hamon, J.-R.; Lapinte, C. Organometallics 1991, 10, 1045. (b) Tenorio, J. M.; Puerta, M. C.; Valerga, P. Organometallics 1994, 13, 3330. (c) Leal, A. J.; Tenorio, J. M.; Puerta, M. C.; Valerga, P. Organometallics 1995, 14, 3839. (d) Hamon, P.; Toupet, L.; Hamon, J.-R.; Lapinte, C. Organometallics 1996, 15, 10.
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43. In the absence of π-acceptor ligands to relieve the increased electron density at the metal center, these low-valent compounds readily activate unsaturated organic substrates. See, for example: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1990, 9, 1925. (b) Abugideiri, F.; Kelland, M. A.; Poli, R.; Rheingold, A. L. Organometallics 1992, 11, 1303. (c) Abugideiri, F.; Kelland, M. A.; Poli, R. Organometallics 1992, 11, 1311. (d) Döhring, A.; Emrich, R.; Goddard, R.; Jolly, P. W.; Krüger, C. Polyhedron 1993, 12, 2671. (e) Jonas, K.; Klusmann, P.; Goddard, R. Z. Naturforsch. B 1995, 50, 394.
44. In the absence of π-acceptor ligands to relieve the increased electron density at the metal center, these low-valent compounds readily activate unsaturated organic substrates. See, for example: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1990, 9, 1925. (b) Abugideiri, F.; Kelland, M. A.; Poli, R.; Rheingold, A. L. Organometallics 1992, 11, 1303. (c) Abugideiri, F.; Kelland, M. A.; Poli, R. Organometallics 1992, 11, 1311. (d) Döhring, A.; Emrich, R.; Goddard, R.; Jolly, P. W.; Krüger, C. Polyhedron 1993, 12, 2671. (e) Jonas, K.; Klusmann, P.; Goddard, R. Z. Naturforsch. B 1995, 50, 394.
45. In the absence of π-acceptor ligands to relieve the increased electron density at the metal center, these low-valent compounds readily activate unsaturated organic substrates. See, for example: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1990, 9, 1925. (b) Abugideiri, F.; Kelland, M. A.; Poli, R.; Rheingold, A. L. Organometallics 1992, 11, 1303. (c) Abugideiri, F.; Kelland, M. A.; Poli, R. Organometallics 1992, 11, 1311. (d) Döhring, A.; Emrich, R.; Goddard, R.; Jolly, P. W.; Krüger, C. Polyhedron 1993, 12, 2671. (e) Jonas, K.; Klusmann, P.; Goddard, R. Z. Naturforsch. B 1995, 50, 394.
46. In the absence of π-acceptor ligands to relieve the increased electron density at the metal center, these low-valent compounds readily activate unsaturated organic substrates. See, for example: (a) Hessen, B.; Meetsma, A.; van Bolhuis, F.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1990, 9, 1925. (b) Abugideiri, F.; Kelland, M. A.; Poli, R.; Rheingold, A. L. Organometallics 1992, 11, 1303. (c) Abugideiri, F.; Kelland, M. A.; Poli, R. Organometallics 1992, 11, 1311. (d) Döhring, A.; Emrich, R.; Goddard, R.; Jolly, P. W.; Krüger, C. Polyhedron 1993, 12, 2671. (e) Jonas, K.; Klusmann, P.; Goddard, R. Z. Naturforsch. B 1995, 50, 394.
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