(Cyanocyclopentadienyl)potassium and -cesium

European Journal of Inorganic Chemistry

Volumn , Issue 5, 2005, Pages 952-958

  Herdtweck, Eberhardt ^a   Köhler, Frank H ^a   Mölle, Rüdiger ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

133Cs NMR spectroscopy; Crystal structure; Cyanocyclopentadienide

Indexed keywords

CESIUM; CHAINS; METAL IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POTASSIUM; SINGLE CRYSTALS;

133CS NMR SPECTROSCOPY; ALKALI-METAL IONS; CROSSLINKED; CRYSTALS STRUCTURES; CYANOCYCLOPENTADIENIDE; NMR-SPECTROSCOPY; SINGLE CRYSTAL X-RAY STRUCTURES; SYNTHESISED; X-RAY STRUCTURE DETERMINATIONS; ZIGZAG CHAINS;

CRYSTAL STRUCTURE;

CESIUM; POTASSIUM;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 16444377152     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400663     Document Type: Article

References (64)

1. a) D. W. Macomber, W. P. Hart, M. D. Rausch, Adv. Organomet. Chem. 1982, 21, 1-55;
2. b) R. L. Halterman, Chem. Rev. 1992, 92, 965-994;
3. c) C. Janiak, H. Schumann, Adv. Organomet. Chem. 1991, 33, 291-379;
4. d) J. Okuda, Top. Curr. Chem. 1992, 160, 97-145;
5. e) N. B. Ivchenko, P. V. Ivchenko, I. E. Nifant'ev, Russ. J. Org. Chem. 2000, 36, 609-637.
6. a) J. Okuda, Comments Inorg. Chem. 1994, 16, 185-205;
7. b) G. Wagner, R. Herrmann, in Ferrocenes (Eds.: A. Togni, T. Hayashi), VCH, Weinheim, 1995, chapter 4;
8. c) R. L. Halterman, in Metallocenes (Eds.: A. Togni, R. L. Halterman), Wiley-VCH, Weinheim. 1998, vol. 1, chapter 8;
9. d) U. Siemeling, Chem. Rev. 2000, 100, 1495-1526.
10. a) D. Peters, J. Chem. Soc., Dalton Trans. 1960, 1832-1837;
11. b) O. W. Webster, J. Am. Chem. Soc. 1966, 88, 3046-3050;
12. c) W. Neukam, W. Grimme, Tetrahedron Lett. 1978, 2201-2204:
13. d) K. Banert, F. Köhler, B. Meier, Tetrahedron Lett. 2003, 44, 3781-3783.
14. a) S. J. Harder, Coord. Chem. Rev. 1998, 176, 17-66;
15. b) P. Jutzi, N. Burford, Chem. Rev. 1999, 99, 969-990.
16. Selected recent examples of heavy alkali-metal cyclopentadienides: c) S. Neander, F. E. Tio, R. Buschmann, U. Behrens, F. Olbrich, J. Organomet. Chem. 1999, 582, 58-65;
17. d) M. J. Harvey, T. P. Hanusa, M. Pink, J. Chem. Soc., Dalton Trans. 2001, 1128-1130;
18. e) W. J. Evans, J. C. Brady, C. H. Fujimoto, D. G. Giarikos, J. W. Ziller, J. Organomet. Chem. 2002, 649, 252-257;
19. f) G. Bai, H. W. Roesky, P. Muller, Bull. Pol. Acad. Sci. Chem. 2002, 50, 1-10;
20. g) S. Kheradmandan, H. W. Schmalle, H. Jacobsen, O. Blacque, T. Fox, H. Berke, M. Gross, S. Decurtins, Chem. Eur. J. 2002, 8, 2526-2533;
21. h) M. L. Cole, C. Jones, P. C. Junk, J. Chem. Soc., Dalton Trans. 2002, 896-905;
22. i) W. J. Evans, D. G. Giarikos, J. W. Ziller, J. Organomet. Chem. 2003, 688, 200-205.
23. 13C NMR-Spektroskopie, Georg Thieme Verlag, Stuttgart, 1984, p. 124 and 277.
24. a) P. Jutzi, W. Leffers, B. Hampel, S. Pohl, W. Saak, Angew. Chem. 1987, 99, 563-564; Angew. Chem. Int. Ed. Engl. 1987, 26, 583-584;
25. a) P. Jutzi, W. Leffers, B. Hampel, S. Pohl, W. Saak, Angew. Chem. 1987, 99, 563-564; Angew. Chem. Int. Ed. Engl. 1987, 26, 583-584;
26. b) W. J. Evans, T. J. Boyle, J. W. Ziller, Organometallics 1992, 11, 3903-3907;
27. c) R. E. Dinnebier, F. Olbrich, G. M. Bendele, Acta Crystallogr., Sect. C 1997, 53, 699-701;
28. d) R. E. Dinnebier, F. Olbrich, S. van Smaalen, P. W. Stephens, Acta Crystallogr., Sect. B 1997, 53, 153-158;
29. e) R. E. Dinnebier, U. Behrens, F. Olbrich, Organometallics 1997, 16, 3855-3858.
30. S. D. Stults, R. A. Anderson, A. Zalkin, J. Am. Chem. Soc. 1989, 111, 4507-4508.
31. P. A. Seewald, G. S. White, D. W. Stephan, Can. J. Chem. 1988, 66, 1147-1152.
32. V. Jordan, U. Behrens, F. Olbrich, E. Weiss, J. Organomet. Chem. 1996, 517, 81-88.
33. M. Massaux, M.-T. Le Bihan, Acta Crystallogr., Sect. B 1976, 32 1586-1589.
34. a) C. Th́taz, C. Wentrup, J. Am. Chem. Soc. 1976, 98, 1258-1259;
35. b) T. Sakaizumi, H. Kikuchi, O. Ohashi, I. Yamaguchi, Bull. Chem. Soc. Jpn. 1987, 60, 3903-3909.
36. R. D. Shannon, Acta Crystallogr, Sect. A 1976, 32 751-767.
37. S. J. Harder, M. H. Prosenc, Angew. Chem. 1996, 108, 101-103; Angew. Chem. Int. Ed. Engl. 1996, 35, 97-99.
38. S. J. Harder, M. H. Prosenc, Angew. Chem. 1996, 108, 101-103; Angew. Chem. Int. Ed. Engl. 1996, 35, 97-99.
39. a) T. K. Hollis, J. K. Burdett, B. Bosnich, Organometallics 1993, 12, 3385-3386;
40. b) T. V. Timofeeva, J.-H. Lii, N. L. Allinger, J. Am. Chem. Soc. 1995, 117, 7452-7459;
41. c) E. P. F. Lee, P. Soldan, T. G. Wright, Inorg. Chem. 2001, 40, 5979-5984;
42. d) V. N. Sapunov, K. Kirchner, R. Schmid, J. Organomet. Chem. 2001, 214, 143-185.
43. M. Kaupp, Angew. Chem. 2001, 113, 3642-3677; Angew. Chem. Int. Ed. 2001, 40, 3535-3565.
44. M. Kaupp, Angew. Chem. 2001, 113, 3642-3677; Angew. Chem. Int. Ed. 2001, 40, 3535-3565.
45. C. Schade, P. von R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169-278.
46. a) S. Mooibroek, R. E. Wasylishen, R. Dickson, G. Facey, B. A. Pettitt, J. Magn. Reson. 1986, 66, 542-545;
47. b) P. W. France, J. Magn. Reson. 1991, 92, 30-44.
48. a) W. P. Power, R. E. Wasylishen, S. Mooibroek, B. A. Pettitt, W. Danchura, J. Phys. Chem. 1990, 94, 591-598;
49. b) J. Skipsted, T. Vosegaard, H. Budsøe, H. J. Jakobsen, J. Phys. Chem. 1996, 100, 14872-14881.
50. W. J. DeWitte, L. Liu, E. Mei, J. L. Dye, A. I. Popov, J. Solution Chem. 1977, 6, 337-348.
51. C. Elschenbroich, J. Schneider, H. Prinzbach, W.-D. Fessner, Organometallics 1986, 5, 2091-2096.
52. a) L. A. Paquette, W. Bauer, M. R. Sivik, M. Bühl, M. Feigel, P. von R. Schleyer, J. Am. Chem. Soc. 1990, 112, 8776-8789;
53. b) N. Hertkorn, F. H. Köhler, Z. Naturforsch., Teil B 1990, 45, 848-856;
54. c) D. Johnels, A. Boman, U. Edlund, Magn. Reson. Chem. 1998, 36, S151-S156.
55. F. H. Köhler, X. Xie, Magn. Reson. Chem. 1997, 35, 487-492.
56. G. Brauer, A. Haas, Handbuch der Präparativen Anorganischen Chemie, Ferdinand Enke Verlag, Stuttgart, 1978, p. 630.
57. a) Data Collection Software for NONIUS κ-CCD devices, Delft, The Netherlands, 1997;
58. b) Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307;
59. c) International Tables for Crystallography, vol. C, 3rd ed. (Eds.: T. Hahn, A. J. C. Wilson), Kluwer Academic Publisher, Dordrecht, Boston, London, 1992;
60. d) G. Artus, W. Scherer, T. Priermeier, E. Herdtweck, STRUX-V: A Program System to Handle X-ray Data, TU München, Garching, Germany, 1997;
61. e) A. L. Spek, PLATON: A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 2001;
62. f) SIR92: A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, J. Appl Crystallogr. 1994, 27, 435-436;
63. g) G. M. Sheldrick, SHELXL-97, University of Göttingen, Göttingen, Germany, 1998;
64. CCDC-246097 (CpCNK) and -246098 (CpCNCs) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.