The Pd4(dppm)4(H)22+ Cluster: A Precatalyst for the Homogeneous Hydrogenation of Alkynes

Inorganic Chemistry

Volumn 43, Issue 2, 2004, Pages 790-796

  Evrard, David ^a,b   Groison, Katherine ^b   Mugnier, Yves ^a   Harvey, Pierre D ^b  

^a UNIVERSITÉ DE BOURGOGNE   (France)

^b UNIVERSITÉ DE SHERBROOKE   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; ALKYNE DERIVATIVE; DIPHENYLETHYNE; PALLADIUM; PHENYL 1 PROPYNE; PHENYLACETYLENE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CONCENTRATION (PARAMETERS); HYDROGENATION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 1642527091     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0347992     Document Type: Article

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66. 3. As alkynes are more reactive than alkenes based on this work, it is possible that hydrogenation reactions for both alkynes and alkenes are slowed to the point that the hydrogenation of alkenes are too slow to be observed in the conditions used.