Reductive elimination of alkanes and arenes from [Pd2R2(μ-H)(μ- dppm)2]PF6 complexes [8]

Journal of the American Chemical Society

Volumn 121, Issue 34, 1999, Pages 7945-7946

  Stockland Jr , Robert A ^a   Anderson, Gordon K ^a   Rath, Nigam P ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; PALLADIUM COMPLEX; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; LETTER; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; TEMPERATURE;

EID: 0345425081     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990815b     Document Type: Letter

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21. 1H} NMR: δ 11.5 (s).
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25. O, I > 2σ(I), GOF = 1.069.
26. + two three-line multiplets centered at 10.5 and 17.1 ppm were observed. Similar patterns were found in the other cases.
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28. The data in Table 1 suggest the possibility of an isokinetic relationship, but a study of the set of Arrhenius plots shows that this is not the case. (a) Petersen, R. C. J. Org. Chem. 1964, 29, 3133-3135. (b) McBane, G. C. J. Chem. Educ. 1998, 75, 919-922.