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Volumn 346, Issue 1, 2004, Pages 63-71

Phosphorus acids as highly efficient promoters for the palladium- phenanthroline catalyzed carbonylation of nitrobenzene to methyl phenylcarbamate

Author keywords

Carbamates; Carbonylation; Homogeneous catalysis; Nitroarenes; Palladium

Indexed keywords

CARBAMIC ACID DERIVATIVE; METHYLPHENYLCARBAMATE; NITROBENZENE; PALLADIUM; PHENANTHROLINE; PHOSPHORUS ACID DERIVATIVE; UNCLASSIFIED DRUG;

EID: 1642486701     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200303143     Document Type: Article
Times cited : (61)

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    • note
    • The absolute amounts of all other reagents, including phenanthroline and phosphoric acid, have been kept constant and equal to the ones in Table 6, except for the CO pressure (100 bar). Nitrobenzene conversion was complete in this experiment; thus even higher TONs should be possible.
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