Adducts of Acetylene and Dimethylacetylenedicarboxylate at Sulfurs in Sulfur-Bridged Incomplete Cubane-Type Tungsten Clusters

Inorganic Chemistry

Volumn 43, Issue 2, 2004, Pages 602-612

  Ide, Yasuhiro ^a   Sasaki, Makoto ^a   Maeyama, Masataka ^a   Shibahara, Takashi ^a  

^a OKAYAMA UNIVERSITY OF SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ACETONITRILE; ACETYLENE DERIVATIVE; ACETYLENEDICARBOXYLIC ACID DIMETHYL ESTER; CUBANE DERIVATIVE; ISOTHIOCYANIC ACID DERIVATIVE; SULFUR; TUNGSTEN;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CONFORMATION; HYDROLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 1642486444     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0349860     Document Type: Article

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64. 1H NMR spectroscopy.
65. a, measured 6.76 ppm, calcd 7.33 ppm (=5.28 + 0.90 (gem COOR) + 1.20 (cis COOR) - 0.05 (trans SR)). 6′: H1, measured 6.13 ppm, calcd 6.28 ppm (=5.28+1.0 (gem SR)); H2, measured 5.22 ppm, calcd 5.23 (=5.28 - 0.05 (trans SR)); H3, measured 5.69 ppm, calcd 5.03 (=5.28 - 0.25 (cis SR)); H4, measured 6.42 ppm, calcd 6.23 ppm (=5.28 + 1.0 (gem SR) - 0.05 (trans SR)).
66. No detailed characterization has been made.