[3+2] Cycloaddition reactions of the phospha-alkyne, ButCP, with a transition metal trisulphide containing terminal thio ligands: Syntheses, crystal and molecular structures of [W(η5-(C5Me5)(S)(S2PCtBu)]2 and [W(η5-(C5Me5)(S)(S2C2 Ph2)]2

Journal of Organometallic Chemistry

Volumn 564, Issue 1-2, 1998, Pages 189-191

  D'Arbeloff, Sarah E ^a   Hitchcock, Peter B ^a   Nixon, John F ^a   Nagasawa, Takayuki ^b   Kawaguchi, Hiroyuki ^b   Tatsumi, Kazuyuki ^b  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

^b NAGOYA UNIVERSITY   (Japan)

Author keywords

Cycloaddition; Thio ligands; Trisulfide

Indexed keywords

EID: 0032516569     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00687-1     Document Type: Article

References (21)

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14. t, 18H).
15. 2=0.203 for all data.
16. 6 requires C, 48.57, H, 4.25, S, 16.21%.
17. w=0.027 (for I>3σI).
18. Barron A.R., Cowley A.H., Hall S.W., Nunn C.M Angew. Chem. Int. Ed. Engl. 27:1988;837.
19. (a) E. Lindner, C. Haase, H.A. Meyer, M. Kemmler, R. Fawzi, M. Steimann, Angew. Chem. Int. Ed. Engl. 32 (1993) 1424.
20. (b) E. Lindner, T. Schlenker, C. Haase, J. Organomet. Chem. 464 (1994) C31.
21. S.E. d'Arbeloff, S. Krill, J.F. Nixon, L. Nyulaszi, M. Regitz, paper in preparation.