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1642342533
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note
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Halogenation from the dizinc was more efficient and consistent than that from the dilithio species; see ref 8.
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22
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1642282413
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note
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Compounds exactly analogous to 6 have been prepared from 2,5-dibromosiloles; see refs 7 and 8.
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23
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For a modified procedure that does not require anhydrous conditions, see: Anastasia, L.; Negishi, E. Org. Lett. 2001, 3, 3111-3113.
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1642376823
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note
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max and quantum yield remained consistent over a broad concentration range (0.1-45 μM).
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30
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1642363691
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note
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It is encouraging that both aminosiloles display noncentrosymmetric packing, which is a requirement for second-harmonic generation in the solid state; see ref 5.
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