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6-coordinated complexes and the cyclometallated systems have been reviewed: I. M. Dixon, J.-P. Collin, J.-P. Sauvage, L. Flamigni, S. Enemas and F. Barigelletti, Chem. Soc., Rev., 2000, 29, 385.
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Examples include terpyridines, phenanthrolines and bipyridines; representative references are, respectively: I. M. Dixon, J.-P. Collin, J.-P. Sauvage, F. Barigelletti and L. Flamigni, Angew. Chem., Int. Ed., 2000, 38, 1292; D. S. Tyson, J. Bialecki and F. N. Castellano, Chem. Commun., 2000, 2355; E. C. Constable, C. E. Housecraft and I. Poleschak, Inorg. Chem. Commun., 1999, 2, 565.
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19
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0034620012
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Examples include terpyridines, phenanthrolines and bipyridines; representative references are, respectively: I. M. Dixon, J.-P. Collin, J.-P. Sauvage, F. Barigelletti and L. Flamigni, Angew. Chem., Int. Ed., 2000, 38, 1292; D. S. Tyson, J. Bialecki and F. N. Castellano, Chem. Commun., 2000, 2355; E. C. Constable, C. E. Housecraft and I. Poleschak, Inorg. Chem. Commun., 1999, 2, 565.
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Examples include terpyridines, phenanthrolines and bipyridines; representative references are, respectively: I. M. Dixon, J.-P. Collin, J.-P. Sauvage, F. Barigelletti and L. Flamigni, Angew. Chem., Int. Ed., 2000, 38, 1292; D. S. Tyson, J. Bialecki and F. N. Castellano, Chem. Commun., 2000, 2355; E. C. Constable, C. E. Housecraft and I. Poleschak, Inorg. Chem. Commun., 1999, 2, 565.
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0000964125
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Bromo-substituted Ru(II), Os(II) and Ir(III) complexes have been used recently in other metal-catalysed coupling reactions; for example, in Sonogashira couplings: P. J. Connors Jr., D. Tzalis, A. L. Dunnick and Y. Tor, Inorg. Chem., 1998, 37, 1121; in Stille couplings: G. R. Pabst, O. C. Pfüller and J. Sauer, Tetrahedron, 1999, 55, 8045; in Negishi couplings: Y. Q. Fang, M. I. J. Poison and G. S. Hanan, Inorg. Chem., 2003, 42, 5; and in homo-coupling reactions catalysed by nickel(o) to give dimeric products: S. Fanni, C. Di Pietro, S. Serroni, S. Campagna and J. G. Vos, Inorg. Chem. Commun., 2000, 3, 42; P. M. Griffiths, F. Loiseau, F. Puntoriero, S. Serroni and S. Campagna, Chem. Commun., 2000, 2297.
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0033603636
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Bromo-substituted Ru(II), Os(II) and Ir(III) complexes have been used recently in other metal-catalysed coupling reactions; for example, in Sonogashira couplings: P. J. Connors Jr., D. Tzalis, A. L. Dunnick and Y. Tor, Inorg. Chem., 1998, 37, 1121; in Stille couplings: G. R. Pabst, O. C. Pfüller and J. Sauer, Tetrahedron, 1999, 55, 8045; in Negishi couplings: Y. Q. Fang, M. I. J. Poison and G. S. Hanan, Inorg. Chem., 2003, 42, 5; and in homo-coupling reactions catalysed by nickel(o) to give dimeric products: S. Fanni, C. Di Pietro, S. Serroni, S. Campagna and J. G. Vos, Inorg. Chem. Commun., 2000, 3, 42; P. M. Griffiths, F. Loiseau, F. Puntoriero, S. Serroni and S. Campagna, Chem. Commun., 2000, 2297.
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23
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0037242351
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Bromo-substituted Ru(II), Os(II) and Ir(III) complexes have been used recently in other metal-catalysed coupling reactions; for example, in Sonogashira couplings: P. J. Connors Jr., D. Tzalis, A. L. Dunnick and Y. Tor, Inorg. Chem., 1998, 37, 1121; in Stille couplings: G. R. Pabst, O. C. Pfüller and J. Sauer, Tetrahedron, 1999, 55, 8045; in Negishi couplings: Y. Q. Fang, M. I. J. Poison and G. S. Hanan, Inorg. Chem., 2003, 42, 5; and in homo-coupling reactions catalysed by nickel(o) to give dimeric products: S. Fanni, C. Di Pietro, S. Serroni, S. Campagna and J. G. Vos, Inorg. Chem. Commun., 2000, 3, 42; P. M. Griffiths, F. Loiseau, F. Puntoriero, S. Serroni and S. Campagna, Chem. Commun., 2000, 2297.
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24
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0034350493
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Bromo-substituted Ru(II), Os(II) and Ir(III) complexes have been used recently in other metal-catalysed coupling reactions; for example, in Sonogashira couplings: P. J. Connors Jr., D. Tzalis, A. L. Dunnick and Y. Tor, Inorg. Chem., 1998, 37, 1121; in Stille couplings: G. R. Pabst, O. C. Pfüller and J. Sauer, Tetrahedron, 1999, 55, 8045; in Negishi couplings: Y. Q. Fang, M. I. J. Poison and G. S. Hanan, Inorg. Chem., 2003, 42, 5; and in homo-coupling reactions catalysed by nickel(o) to give dimeric products: S. Fanni, C. Di Pietro, S. Serroni, S. Campagna and J. G. Vos, Inorg. Chem. Commun., 2000, 3, 42; P. M. Griffiths, F. Loiseau, F. Puntoriero, S. Serroni and S. Campagna, Chem. Commun., 2000, 2297.
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84889530612
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For example, in 4′-phenylterpyridine: E. C. Constable, J. Lewis, M. C. Liptrot and P. R. Raithby, Inorg. Chim. Acta, 1990, 178, 47; and in related derivatives: E. C. Constable, F. K. Khan, P. R. Raithby and V. E. Marquez, Acta Crystallogr., Sect. C, 1992, C48, 932.
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See, for example: S. D. Cummings and R. Eisenberg, J. Am. Chem. Soc., 1996, 118, 1949; unfortunately, the low solubility of the complex in solvents less polar than acetonitrile, and the dearth of appropriate solvents with polarities intermediate between those of acetonitrile and water, prevents a thorough study of the solvato-chromism.
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1642353524
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note
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In this and other respects, the properties of the homoleptic, aminosubstituted complexes are quite different from those of the complexes reported here, and will be discussed, together with their synthesis, elsewhere: W. Leslie, R. A. Poole and J. A. G. Williams, manuscript in preparation.
-
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-
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44
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1642418297
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note
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Based on data in ref. 4 and 7 and further unpublished results on pyridyl-substituted complexes.
-
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46
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0037693738
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2-] unit by the iridium complex: J. M. Haider, R. M. Williams, L. De Cola and Z. Pikramenou, Angew. Chem., Int. Ed., 2003, 42, 1830.
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