Ring-opening protonolysis of sila[1]ferrocenophanes as a route to stabilized silylium ions

Chemistry - A European Journal

Volumn 11, Issue 7, 2005, Pages 1989-2000

  Bourke, Sara C ^a   MacLachlan, Mark J ^b   Lough, Alan J ^a   Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

^b UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

Ferrocenophanes; Ring strain; Sandwich complexes; Silanes; Silylium ions

Indexed keywords

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; SILICON COMPOUNDS; SINGLE CRYSTALS; SUBSTITUTION REACTIONS; X RAY DIFFRACTION ANALYSIS;

FERROCENOPHANE; FERROCENYLSILANE; RING-STRAIN; SANDWITCH COMPLEXES;

AROMATIC COMPOUNDS;

ANION; FERROCENE DERIVATIVE; FLUORIDE ION; LEWIS ACID; PYRIDINE; SILA[1]FERROCENOPHANE DERIVATIVE; SILICON; SILICON DERIVATIVE; SILYLIUM ION; TETRAKIS[3,5 BIS(TRILUOROMETHYL)PHENYL]BORATE; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CRYSTAL STRUCTURE; LOW TEMPERATURE; LYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; PROTONOLYSIS; RING OPENING; SILICON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

CRYSTALLOGRAPHY, X-RAY; FERROUS COMPOUNDS; IRON; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; ORGANOSILICON COMPOUNDS; PROTONS; REFERENCE STANDARDS;

EID: 15944407143     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400859     Document Type: Article

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