Cis- and trans-strapped calix[4]pyrroles bearing phthalamide linkers: Synthesis and anion-binding properties

Journal of Organic Chemistry

Volumn 70, Issue 6, 2005, Pages 2067-2074

  Lee, Chang Hee ^a   Lee, Jin Suk ^a   Na, Hee Kyung ^a   Yoon, Dae Wi ^a   Miyaji, Hidekazu ^a   Cho, Won Seob ^b   Sessler, Jonathan L ^b  

^a Kangwon National University   (South Korea)

^b UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; CALORIMETRY; DERIVATIVES; HYDROGEN BONDS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STOICHIOMETRY; SYNTHESIS (CHEMICAL); TITRATION;

ANION BINDING; ISOTHERMAL TITRATION CALORIMETRY (ITC); PHTHALAMIDE; PYRROLES;

NITROGEN COMPOUNDS;

ANION; CALIXARENE; PHTHALAZINE DERIVATIVE; PYRROLE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CIS TRANS ISOMERISM; HYDROGEN BOND; ISOTHERMAL TITRATION CALORIMETRY; PARTICLE SIZE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS;

ANIONS; CALIXARENES; HALOGENS; MODELS, CHEMICAL; MOLECULAR CONFORMATION; PHTHALIMIDES; PORPHYRINS; STEREOISOMERISM;

EID: 15444380600     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0487146     Document Type: Article

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24. Isothermal titration calorimetery (ITC) measurements were performed as follows: Solutions of the chosen receptor in rigorously dry acetonitrile were made up so as to provide a receptor concentration range of 0.1-1 mM. These solutions were then individually titrated with the appropriate alkylammonium salts at 30 ± 0.01°C. The original heat pulses were normalized using reference titrations carried out using the same salt solution but pure solvent, as opposed to a solution containing the receptor. The values recorded in Table 1 are the average result of at least three separate titrations carried out using at least two different concentrations.