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43
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2642612992
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1H NMR titration methods analogous to those reported in ref. [11]
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1H NMR titration methods analogous to those reported in ref. [11].
-
-
-
-
45
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2642610464
-
-
note
-
[11] In this system, the amide bond must always point directly away from the pyrrolic hydrogen-bonding array of the calixpyrrole, making it unlikely that the amide NH contributes significantly to the anion chelation process. In fact, the chemical shift of the amide proton alters by only 0.5 ppm in the presence of 6.0 molar equiv of chloride anions.
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48
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49
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2642704410
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note
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-1, mobile phase l0mM phosphate buffer, pH7.1, column temperature 25 °C, UV detection at 254 nm) gel B gave a baseline separation whereas gel S did not.
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