Isocyanide insertion reactivity of dinuclear niobium and tantalum imido complexes: X-ray crystal structure of [{Nb(η5 -C5H4SiMe3)(CH2Ph) 2}2(μ-1,4-NC6H4N)]

Journal of Organometallic Chemistry

Volumn 689, Issue 7, 2004, Pages 1304-1314

  Prashar, Sanjiv ^a   Fajardo, Mariano ^a   Garcés, Andrés ^a   Dorado, Iván ^a   Antiñolo, Antonio ^b   Otero, Antonio ^b   López Solera, Isabel ^b   López Mardomingo, Carmen ^c  

^a UNIVERSIDAD REY JUAN CARLOS   (Spain)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

^c UNIVERSITY OF ALCALÁ   (Spain)

Author keywords

Imido; Insertion reactions; Isocyanides; Niobium; Tantalum

Indexed keywords

ALKYL GROUP; CYCLOPENTADIENE DERIVATIVE; ISOCYANIC ACID DERIVATIVE; METAL COMPLEX; NIOBIUM; NITROGEN; PYRROLE DERIVATIVE; TANTALUM;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

INSERTION SEQUENCES;

EID: 1542471517     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.01.029     Document Type: Article

References (46)

1. Creutz C. Prog. Inorg. Chem. 30 1983 1
2. Creutz C. Taube H. J. Am. Chem. Soc. 91 1969 3988
3. Haim A. Prog. Inorg. Chem. 30 1983 273
4. Meyer T.J. Prog. Inorg. Chem. 30 1983 389
5. Meyer T.J. in: Brown D.B. (Ed.), Mixed-Valence Compounds 1980 75 Reidel Dordrecht
6. Miller J.E. Adv. Chem. Ser. 150 1976 18
7. Maatta E.A. Devore D.D. Angew. Chem., Int. Ed. Engl. 27 1988 569
8. Maatta E.A. Kim C. Inorg. Chem. 28 1989 624
9. Rosen R.K. Anderson R.A. Edelstein N.M. J. Am. Chem. Soc. 112 1990 4588
10. Clegg W. Errington R.J. Hockless D.C.R. Kirck J.M. Redshaw C. Polyhedron 11 1992 381
11. Redshaw C. Wilkinson G. Hussain-Bates B. Hursthouse M.B. J. Chem. Soc., Dalton Trans. 1992 555
12. Hogart G. Mallors R.L. Norman T.J. J. Chem. Soc., Chem. Commun. 1993 1721
13. Wigley D.E. Prog. Inorg. Chem. 42 1994 239
14. Antiñolo A. Fajardo M. Otero A. Prashar S. Eur. J. Inorg. Chem. 2003 17
15. (a) Antiñolo A. Carrillo-Hermosilla F. Otero A. Fajardo M. Garcés A. Gómez-Sal P. López-Mardomingo C. Martín A. Miranda C. J. Chem. Soc., Dalton Trans. 1998 59
16. Dorado I. Garcés A. López-Mardomingo C. Fajardo M. Rodríguez A. Antiñolo A. Otero A. J. Chem. Soc., Dalton Trans. 2000 2375
17. Antiñolo A. Dorado I. Fajardo M. Garcés A. Kubicki M.M. López-Mardomingo C. Otero A. Dalton Trans. 2003 910
18. A. Antiñolo, I. Dorado, M. Fajardo, A. Garcés, I. López-Solera, C. López-Mardomingo, M.M. Kubicki, A. Otero, S. Prashar, Eur. J. Inorg. Chem., in press
19. Durfee L.D. Rothwell I.P. Chem. Rev. 88 1988 1059
20. Abel E.W. Stone F.G.A. (Eds.), Wilkinson G. Comprehensive Organometallic Chemistry, second ed vol. 5 1995 Pergamon Oxford
21. Moloy K.G. Fagan P.J. Manríquez J.M. Marks T.J. J. Am. Chem. Soc. 108 1986 56
22. Chamberlain L.R. Durfee L.D. Fanwick P.E. Kobriger L. Latesky S.L. McMullen A.K. Rothwell I.P. Folting K. Huffman J.C. Streib W.E. Wang R. J. Am. Chem. Soc. 109 1987 390
23. Chamberlain L.R. Rothwell I.P. Huffman J.C. J. Chem. Soc., Chem. Commun. 1986 1203
24. Williams D.N. Mitchell J.P. Poole A.D. Siemeling U. Clegg W. Hockless D.C.R. O'Neil P.A. Gibson V.C. J. Chem. Soc., Dalton Trans. 1992 739
25. Galakhov M.V. Gómez M. Jiménez G. Pellinghelli M.A. Royo P. Tiripicchio A. Organometallics 13 1994 1564
26. Humphries M.J. Green M.L.H. Leech M.A. Gibson V.C. Jolly M. Williams D.N. Elsegood M.R.J. Clegg W. J. Chem. Soc., Dalton Trans. 2000 4044
27. Humphries M.J. Green M.L.H. Douthwaite R.E. Rees L.H. J. Chem. Soc., Dalton Trans. 2000 4555
28. Poole A.D. Williams D.N. Kenwright A.M. Gibson V.C. Clegg W. Hockless D.C.R. O'Neil P.A. Organometallics 12 1993 2549
29. Burckhardt U. Tilley T.D. J. Am. Chem. Soc. 121 1999 6328
30. Nikonov G.I. Mountford P. Green J.C. Cooke P.A. Leech M.A. Blake A.J. Howard J.A.K. Lemenovskii D.A. Eur. J. Inorg. Chem. 2000 1917
31. Antiñolo A. Espinosa P. Fajardo M. Gómez-Sal P. López-Mardomingo C. Martin-Alonso A. Otero A. J. Chem. Soc., Dalton Trans. 1995 1007
32. See for example: Pellecchia C. Immirzi A. Pappalardo D. Peluso A. Organometallics 13 1994 3773
33. Erker G. Acc. Chem. Res. 17 1984 103
34. Antiñolo A. Fernández-Galán R. Gallego B. Otero A. Prashar S. Rodríguez A.M. Eur. J. Inorg. Chem. 2003 2626
35. Antiñolo A. Fernández-Galán R. Orive I. Otero A. Prashar S. Eur. J. Inorg. Chem. 2002 2470
36. Castro A. Galakhov M.V. Gómez M. Gómez- Sal P. Martín A. Sánchez F. J. Organomet. Chem. 595 2000 36
37. Kloppenburg L. Petersen J.L. Organometallics 16 1997 3548
38. Putzer M.A. Neumüller B. Dehnicke K. Z. Anorg. Allg. Chem. 624 1998 57
39. Planalp R.P. Andersen R.A. Organometallics 2 1983 1675
40. Huff R.L. Wang S.-Y. Abboud K. Boncella J.M. Organometallics 16 1997 1779
41. Dormond A. Aaliti A. Moise A. J. Chem. Soc., Chem. Commun. 1985 1231
42. Zanella P. Brianese N. Castellato U. Ossala F. Porchin M. Rosetto G. Graziani R. J. Chem. Soc., Dalton Trans. 1987 2039
43. Gountchev T.C. Tilley T.D. J. Am. Chem. Soc. 19 1997 12831
44. Alcalde M.I. Gómez-Sal P. Royo P. Organometallics 18 1999 546
45. Sheldrick G.M. Acta Crystallogr. Sect. A 46 1990 467
46. Sheldrick G.M. Program for the Refinement of Crystal Structures from Diffraction Data 1997 University of Göttingen Göttingen, Germany