Double isocyanide insertion and C,C-coupling reaction of [(C5Me4)SiMe2(N-t-Bu)]ZrMe2. Structural characterization of the two 1,4-diaza-5-zirconacyclopentene ring Conformations for [(C5Me4)SiMe2(N-t-Bu)]Zr[N(R)C(Me)=C(Me)N(R)] complexes

Organometallics

Volumn 16, Issue 15, 1997, Pages 3548-3556

  Kloppenburg, Lioba ^a   Petersen, Jeffrey L ^a  

^a WEST VIRGINIA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000043053     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9610760     Document Type: Article

References (47)

1. (a) McMullen, A. K.; Rothwell, I. P.; Huffman, J. C. J. Am. Chem. Soc. 1985, 107, 1072.
2. (b) Chamberlain, L. R.; Durfee, L. D.; Fanwick, P. E.; Kobriger, L. M.; Latesky, S. L.; McMullen, A. K.; Steffey, B. D.; Rothwell, I. P.; Folting, K.; Huffman, J. C. J. Am. Chem. Soc. 1987, 109, 6068.
3. (c) Durfee, L. D.; Rothwell, I. P. Chem. Rev. 1988, 88, 1059 and references cited therein.
4. (a) Berg, F. J.; Petersen, J. L. Organometallics 1989, 8, 2461.
5. (b) Berg, F. J.; Petersen, J. L. Organometallics 1991, 10, 1599.
6. (c) Berg, F. J.; Petersen, J. L. Tetrahedron 1992, 48, 4749.
7. (d) Valero, C.; Grehl, M.; Wingbermühle, D.; Kloppenburg, L.; Carpenetti, D.; Erker, G.; Petersen, J. L. Organometallics 1994, 13, 415.
8. (a) Berg, F. J.; Petersen, J. L. Organometallics 1993, 12, 3890.
9. (b) Kloppenburg, L.; Petersen, J. L. Polyhedron 1995, 14, 69.
10. Tatsumi, K.; Nakamura, A.; Hofmann, P.; Stauffert, P.; Hoffmann, R. J. Am. Chem. Soc. 1985, 107, 4440.
11. (a) Lappert, M. F.; Luong-Thi, N. T.; Milne, C. R. C. J. Organomet. Chem. 1979, 174, C35.
12. (b) Wolczanski, P. T.; Bercaw, J. E. J. Am. Chem. Soc. 1979, 101, 6450.
13. (c) Lyszak, E. L.; O'Brien, J. P.; Kort, D. A.; Hendges, S. K.; Redding, R. N.; Bush, T. L.; Hermen, M. S.; Renkema, K. B.; Silver, M. E.; Huffman, J. C. Organometallics 1993, 12, 338.
14. 2-iminoacyls include: (a) Bocarsly, J. R.; Floriani, C.; Chiesa-Villa, A.; Guastini, C. Organometallics 1986, 5, 2380. (b) Hessen, B.; Blenkers, J.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1989, 8, 830. (c) Fandos, R.; Meetsma, A.; Teuben, J. H. Organometallics 1991, 10, 2665.
15. 2-iminoacyls include: (a) Bocarsly, J. R.; Floriani, C.; Chiesa-Villa, A.; Guastini, C. Organometallics 1986, 5, 2380. (b) Hessen, B.; Blenkers, J.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1989, 8, 830. (c) Fandos, R.; Meetsma, A.; Teuben, J. H. Organometallics 1991, 10, 2665.
16. 2-iminoacyls include: (a) Bocarsly, J. R.; Floriani, C.; Chiesa-Villa, A.; Guastini, C. Organometallics 1986, 5, 2380. (b) Hessen, B.; Blenkers, J.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1989, 8, 830. (c) Fandos, R.; Meetsma, A.; Teuben, J. H. Organometallics 1991, 10, 2665.
17. (a) Shapiro, P. J.; Bunel, E. E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867.
18. (b) Piers, W. E.; Shapiro, P. J.; Bunel, E. E.; Bercaw, J. E. Synlett 1990, 2, 74.
19. (c) Shapiro, P. J.; Cotter, W. D.; Schaefer, W. P.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1994, 116, 4623.
20. (a) Canich, J. M. Eur. Pat. Appl. EP-420-436-A1, 1990.
21. (b) Canich, J. M. U.S. Patent 5,026,798, 1991.
22. (c) Canich, J. M.; Hlatky, G. G.; Turner, H. W. PCT Int. Appl. WO92-00333, 1992.
23. (d) Stevens, J. C.; Timmers, F. J.; Wilson, D. R.; Schmidt, G. F.; Nickias, P. N.; Rosen, R. K.; Knight, G. W.; Lai, S. Eur. Pat. Appl. EP-416-815-A2, 1991.
24. (e) Campbell, R. E., Jr. U.S. Patent 5,066,741, 1991.
25. (f) LaPointe, R. E. European Patent 468651, 1991.
26. Kloppenburg, L; Petersen, J. L. Organometallics 1996, 15, 7.
27. Setukowski, D. G.; Stucky, G. D. Inorg. Cfiem, 1975, 14, 2192.
28. Schuster, R. E.; Scott, J. E.; Casanova, J., Jr. Org. Synth. 1973, 5, 773.
29. Carpenetti, D. W.; Kloppenburg, L.; Kupec, J. T.; Petersen, J. L. Organometallics 1996, 15, 1572.
30. Skoog, D. A.; West, D. M.; Holler, F. J. Analytical Chemistry, an Introduction, 6th ed.; Saunders College Publishing: Philadelphia, PA, 1994; Appendix 6.
31. XSCANS (version 2.0) is a diffractometer control system developed by Siemens Analytical X-ray Instruments, Madison, WI.
32. SHELXL-93 is a FORTRAN-77 program developed by Professor G. Sheldrick (Institut für Anorganische Chemie, University of Göttingen, D-37077 Göttingen, Germany) for single-crystal X-ray structural analyses.
33. Durfee, L. D.; McMullen, A. K.; Rothwell, I. P. J. Am. Chem. Soc. 1988, 110, 1463.
34. c ≫ 150°C, respectively.
35. (a) Reger, D. L.; Tarquini, M. E.; Lebioda, L. Organometallics 1983, 2, 1763.
36. (b) Erker, G.; Korek, U.; Petersen, J. L. J. Organomet. Chem. 1988, 355, 121.
37. (c) Bristow, G. S.; Lappert, M. F.; Atwood, J. L.; Hunter, W. E. Unpublished results described in Chemistry of Organozirconium and Hafnium Compounds; Cardin, D. F., Lappert, M. F., Raston, C. L., Eds.; Wiley, New York, 1986.
38. Chamberlain, L. R.; Durfee, L. D.; Fanwick, P. E.; Kobriger, L.; Latesky, S. L.; McMullen, A. K.; Rothwell, I. P.; Folting, K.; Huffman, J. C.; Streib, W. E.; Wang, R. J. Am. Chem. Soc. 1987, 109, 390.
39. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
40. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
41. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
42. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
43. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
44. 2; Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
45. Scholz, J.; Dlikan, M.; Ströhl, D.; Dietrich, A.; Schumann, H.; Thiele, K.-H. Chem. Ber. 1990, 123, 2279.
46. Erker, G.; Krüger, C.; Müller, G. Adv. Organomet. Chem. 1985, 24, 1 and references cited therein.
47. Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, T. J.; Deck, P. A.; Stern, C. L. Organometallics 1995, 14, 3132.