Influence of a solubility-enhancing agent (cyclodextrin) on NAPL-water partition coefficients, with implications for partitioning tracer tests

Water Resources Research

Volumn 39, Issue 5, 2003, Pages

  Dugan, Pamela J ^a   McCray, John E ^a   Thyne, Geoffrey D ^a  

^a Department of Geology and Geological Engineering   (United States)

Author keywords

Cyclodextrin; NAPL; Partition coefficients; Partitioning tracer tests; Remediation

Indexed keywords

ALCOHOLS; ESTIMATION; MATHEMATICAL MODELS; REMEDIATION; SOLUBILITY; SUGAR (SUCROSE);

CYCLODEXTRINS; WATER PARTITIONING COEFFICIENT;

WATER RESOURCES;

GROUNDWATER POLLUTION; NONAQUEOUS PHASE LIQUID; PARTITION COEFFICIENT; REMEDIATION; TRACER;

EID: 1542436550     PISSN: 00431397     EISSN: None     Source Type: Journal    
DOI: 10.1029/2002WR001672     Document Type: Article

References (27)

1. Annable, M. D., P. S. C. Rao, K. Hatfield, W. D. Graham, and C. G. Enfield, Partitioning tracer tests for measuring residual NAPLs for field-scale test results, J. Environ. Eng., 124(6), 498-503, 1998.
2. Blanford, W. J., M. L. Barackman, T. B. Boving, E. J. Klingel, G. R. Johnson, and M. L. Brusseau, Cyclodextrin-enhanced vertical flushing of a trichloroethene contaminated aquifer, Ground Water Monit. Rem., 21(1), 58-66, 2001.
3. Boving, T. B., and J. E. McCray, Cyclodextrin-enhanced remediation of organic and metal contaminants in porous media and ground water, Remediation, 10(2), 59-83, 2000.
4. Boving, T. B., W. L. Blanford, M. L. Brusseau, and J. E. McCray, Cyclodextrin enhanced removal of DNAPL in the field under unconstrained conditions, Geol. Soc. Am. Bull., 34(6), 2002.
5. Cain, B. R., G. R. Johnson, J. E. McCray, W. J. Blanford, and M. L. Brusseau, Partitioning tracer tests for evaluating remediation performance, Ground Water, 38(5), 752-761, 2000.
6. Cho, J., M. D. Annable, and P. S. C. Rao, Influence of residual cosolvent and surfactant on estimating NAPL saturation using partitioning tracers (abstract), Eos Trans. AGU, 81(48), Fall Meet. Suppl., Abstract H71B-04, 2000.
7. Falta, R. W., C. M. Lee, S. E. Brame, E. Roeder, J. T. Coates, C. Wright, A. L. Wood, and C. G. Enfield, Field test of high molecular weight alcohol flushing for subsurface nonaqueous phase liquid remediation, Water Resour. Res., 35(7), 2095-2108, 1999.
8. Gierke, J. S., D. L. Sanders, and D. L. Perram, Laboratory studies of aqueous partitioning tracer tests for measuring nonaqueous phase liquid volumes, Water Environ. Res., 71(4), 465-474, 1999.
9. Istok, J. D., J. A. Field, M. H. Scroth, B. M. Davis, and V. Dwarakanath, Single-well "push-pull" partitioning tracer test for NAPL detection in the subsurface, Environ. Sci. Technol., 36(12), 2708-2716, 2002.
10. Jawitz, J. W., M. D. Annable, P. S. C. Rao, and D. Rhue, Field implementation of a Winsor type 1 surfactant/alcohol mixture for in situ solubilization of a complex LNAPL as a single-phase microemulsion, Environ. Sci. Technol., 32(4), 523-530, 1998.
11. Jawitz, J. W., R. K. Sillan, M. D. Annable, P. S. C. Rao, and K. Warner, Insitu alcohol flushing of a DNAPL source zone at a dry cleaner site, Environ. Sci. Technol., 34(17), 3722-3729, 2000.
12. Jin, M., M. Delshad, V. Dwarakanath, D. C. McKinney, G. A. Pope, K. Sepehrnoori, C. Tilberg, and R. E. Jackson, Partitioning tracer test for detection, estimation, and remediation performance assessment of subsurface nonaqueous phase liquids, Water Resour. Res., 31(5), 1201-1211, 1995.
13. Knox, R. C., B. J. Shiau, D. A. Sabatini, and J. H. Harwell, Field demonstration studies of surfactant enhanced solubilization and mobilization at Hill AFB, Utah, in Field Testing of Innovative Subsurface Remediation: Physical, Chemical, and Characterization Technologies, ACS Symp. Ser., vol. 725, edited by M. L. Brusseau et al., pp. 49-63, Am. Chem. Soc., Washington, D. C., 1999.
14. Lee, C. M., S. Meyers, C. Wright, J. Coates, P. Haskell, and R. W. Falta, NAPL compositional changes influence partitioning coefficients, Environ. Sci. Technol., 32(22), 3574-3578, 1998.
15. McCray, J. E., and M. L. Brusseau, Cyclodextrin-enhanced in-situ flushing of multiple-component immiscible organic liquid contamination at the field scale: Mass-removal effectiveness, Environ. Sci. Technol., 32(9), 1285-1293, 1998.
16. McCray, J. E., and M. L. Brusseau, Enhanced in-situ flushing of multiple-component immiscible organic liquid contamination at the field scale using cyclodextrin: Mass-transfer phenomena, Environ. Sci. Technol., 33(1), 89-95, 1999.
17. McCray, J. E., and P. J. Dugan, Nonideal equilibrium dissolution of trichloroethene from a decane-based NAPL mixture: Experimental and modeling investigation, Water Resour. Res., 38(7), 1097, doi:10.1029/ 2001WR000883, 2002.
18. McCray, J. E., T. Boving, and M. Brusseau, Enhanced dissolution of hydrophobic organic compounds with implications for aquifer remediation, Ground Water Monit. Rem., 20(1), 94-103, 2000.
19. Meinardus, H. W., V. Dwarakanath, J. Ewing, G. J. Hirasaki, R. E. Jackson, M. Jin, J. S. Ginn, J. T. Londergran, C. A. Miller, and G. A. Pope, Performance assessment of NAPL remediation in heterogeneous alluvium, J. Contam. Hydrol., 54, 173-193, 2002.
20. Nelson, N. T., and M. L. Brusseau, Field study of the partitioning tracer method for detection of dense nonaqueous phase liquid in a trichloroethene-contaminated aquifer, Environ. Sci. Technol., 30(9), 2859-2863, 1996.
21. Rao, P. S. C., M. D. Annable, R. K. Sillan, D. Dai, K. Hatfield, and W. D. Graham, Field-scale evaluation of in-situ cosolvent flushing for enhanced aquifer remediation, Water Resour. Res., 33(12), 2673-2686, 1997.
22. Valocchi, A. J., Validity of the local equilibrium assumption for modeling sorbing solute transport through homogeneous soils, Water Resour. Res., 21(6), 808-820, 1985.
23. Van Genuchten, M. T., A closed-form equation for predicting the hydraulic conductivity of unsaturated soil, Soil Sci. Soc. Am. J., 44, 892, 1980.
24. Vane, L., and S. L. Yeh, Site-specific verification of surfactant-cosolvent flushing, in Performance Verification of in Situ Remediation Technologies, Rep. EPA 542-R-02-002, edited by R. L. Siegrist and B. Satijn, pp. 59-78, Environ. Prot. Agency, Washington, D. C., 2002.
25. Wang, P., V. Searakanath, B. A. Rouse, G. A. Pope, and K. Sepehmoori, Partition coefficients for alcohol tracers between nonaqueous-phase liquids and water from UNIFAC-solubility method, Adv. Water Resour., 21(2), 171-181, 1997.
26. Wilson, R. D., and D. M. Mackay, Direct determination of residual non-aqueous phase liquids in the saturated zone using SF6 as a partitioning tracer, Environ. Sci. Technol., 29(5), 1255-1258, 1995.
27. Young, C., R. E. Jackson, M. Jin, J. T. Londergan, P. E. Mariner, G. A. Pope, F. J. Anderson, and T. Houk, Characterization of a TCE DNAPL zone in alluvium by partitioning tracers, Ground Water Monit. Rem., 19(1), 84-94, 1999.