Unusually Large Primary 2H/1H Kinetic Isotope Effects Accompanying a syn-β-H Elimination Reaction in a σ-Alkyl-Palladium Complex

Journal of the American Chemical Society

Volumn 126, Issue 9, 2004, Pages 2690-2691

  Lloyd Jones, Guy C ^a   Slatford, Paul A ^a  

^a Cantock's Close   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ISOTOPE; PALLADIUM COMPLEX;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; DISSOCIATION; ELIMINATION REACTION; EQUILIBRIUM CONSTANT; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOSPECIFICITY;

EID: 1542317841     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039349n     Document Type: Article

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23. Similar, but not identical, values were obtained with other bases (see Supporting Information), but in all cases these values are of significant magnitude for contributions by secondary isotope effects to be minor.
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