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7,7-Dibutylbicyclo[4.1.0]heptane and 7,7-dimethylbicyclo-[4.1.0]heptane are synthesized according to the reported procedure: Corey, E. J.; Posner, G. H. J. Am. Chem. Soc. 1968, 90, 5615.
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25
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15244356778
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note
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13C NMR peak at 30 ppm. It is assigned to the polyethylene formed after consumption of 7,7-dimethylbicyclo-[4.1.0]heptane.
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27
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15244362702
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note
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Polymerization of methylenecyclopropane catalyzed by Zr and Ni complexes was proposed to involve the 1,2-insertion of the monomer into the M-C bond. See refs 4, 5, and 7.
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28
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15244346415
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note
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Homopolymerization of 7-methylenebicyclo[4.1.0]heptane (0.18 g) using the Co complex ([Co] = 1.7 mM) and MMAO ([monomer]/[Co]/[Al] = 200/1/300) at -40°C produced 0.028 g of polymer (16% yield) after 1 h. The amount of the homopolymer is much smaller than the copolymer obtained from the reaction under 1 atm of ethylene atmosphere (0.18 g).
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29
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0000848348
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13C NMR of (Z)- and (E)-2-cyclohexyl-2-butene: (a) Vedejs, E.; Cabaj, J.; Peterson, M. J. J. Org. Chem. 1993, 58, 6509.
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0001559081
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0000163018
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The assignment of the NMR spectra of the products was confirmed by comparison of them with the compounds having similar structures. See ref 16 and Apparu, M.; Crandall, J. K. J. Org. Chem. 1984, 49, 2125.
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