Suzuki-miyaura cross-coupling of benzylic carbonates with arylboronic acids

Organic Letters

Volumn 7, Issue 5, 2005, Pages 945-947

  Kuwano, Ryoichi ^a   Yokogi, Masashi ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,5 BIS(DIPHENYLPHOSPHINO)PENTANE; BENZENE DERIVATIVE; BENZILIC ACID; BORONIC ACID DERIVATIVE; CARBONIC ACID DERIVATIVE; METHANE; PALLADIUM; PALLADIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; SUZUKI REACTION; SYNTHESIS;

EID: 15044361090     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol050078q     Document Type: Article

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29. 1-benzyl)palladium.
30. 3 to 2a. no formation of 3a was observed. The acidic proton of boronic acid might cause hydrolysis of Pd-OR bond of the intermediate C in Scheme 2.
31. Relative reactivities of 1a,c,d and 2a,b,c were estimated by competitive experiments using 2a and 1a, respectively. See Supporting Information.
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