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Volumn , Issue 5, 2005, Pages 797-802

Synthesis and structural characterization of highly fluorinated sulfimides and sulfoximides as functional building blocks for materials science

Author keywords

Conformation analysis; Liquid crystals; Materials science; Organofluorine chemistry; Organosulfur chemistry

Indexed keywords

IMIDE; ORGANOFLUORINE DERIVATIVE; ORGANOSULFUR DERIVATIVE; SULFIMIDE DERIVATIVE; SULFOXIMIDE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 15044342538     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200400702     Document Type: Article
Times cited : (46)

References (29)
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    • note
    • NI = 92.8 °C, Δε = 5.3, Δn = 0.0964). The extrapolated values are corrected empirically for differences in the order parameter that are induced by the analyte. For the pure substances, the melting points were identified by DSC.
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    • The energies of the conformers A, B, and C were calculated at the B3LYP/6-31G*//B3LYP/ 6-31G* level of theory, including zero point energy correction, b) Pictures: MOLEKEL 4.2: P. Flükinger, H. P. Lüthi, S. Portmann, J. Weber, Swiss Center for Scientific Computing, Manno, Switzerland, 2002.
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    • note
    • -1, R(F) = 4.90% for 3075 observed independent reflections (4.35° ≤ θ ≤ 26.37°);
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    • -1, R(F) = 5.55% for 4096 observed independent reflections (3.16° ≤ θ 30.05°);
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    • c) CCDC-242383 (8) and -242384 (9) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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    • For a detailed discussion on arene-perfluoroarene interactions, see: E. A. Meyer, R. K. Castellano, F. Diederich, Angew. Chem. 2003, 115, 1244-1287; Angew. Chem. Int. Ed. 2003, 42, 1210-1250.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.