Solid-state studies of the Horner-Wittig reagent [{{Ph2P(O)} 2CHLi·(THF)}2·THF] and its mixed-anion intermediate [{{Ph2P(O)}2CHLi}4·{Ph 2P(O)2Li}2·8C6H6] formed by reaction with dioxygen

Polyhedron

Volumn 23, Issue 16, 2004, Pages 2499-2506

  Nassar, Roger ^a   Noll, Bruce C ^a   Henderson, Kenneth W ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

Alkali metals; Chelates; Lithium; O Ligands; Phosphorus carbon bond cleavage

Indexed keywords

AGGREGATES; CARBON; CRYSTAL STRUCTURE; LITHIUM COMPOUNDS; NEGATIVE IONS; REACTION INTERMEDIATES; X RAY CRYSTALLOGRAPHY;

BOND CLEAVAGES; CARBON BOND; CHELATE; COMPLEX 1; DIOXYGENS; METHYLENE BRIDGE; MIXED ANION; O LIGANDS; PHOSPHORUS-CARBON BOND CLEAVAGE; WITTIG REAGENTS;

CHELATION;

ALKALI METAL; CHELATE; LITHIUM DERIVATIVE; OXYGEN;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; HORNER REACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 14344257554     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2004.08.017     Document Type: Article

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