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Volumn 44, Issue 4, 2005, Pages 819-821

The first example of solvothermally synthesized thioantimonates(V) with ethylenediamine coordinated lanthanide(III): [Sm(en)4]SbS 4·0.5en and [Sm(en)3(H2O)(μ-SbS 4)]∞

Author keywords

[No Author keywords available]

Indexed keywords

ANTIMONY DERIVATIVE; ETHYLENEDIAMINE; LANTHANIDE; SAMARIUM; SULFUR; THIOANTIMONATE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 13944284471     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0484957     Document Type: Article
Times cited : (68)

References (34)
  • 27
    • 13944269513 scopus 로고    scopus 로고
    • note
    • 3 was added to the resulting solution, the solvothermal reaction was carried on for 5 days at the same temperature (yield 55% based on Sb).
  • 28
    • 13944257357 scopus 로고    scopus 로고
    • note
    • 2 using SHELXL-97 (Sheldrick, G. M. University of Göttingen). For 1, 243 variables; R1 for 5035 reflections [1 > 2σ(I)] = 0.0300, wR2 for all 5225 data = 0.0605, GOF 1.255. For 2, 94 variables; R1 for 2121 reflections [I > 2σ(I)] = 0.0214, wR2 for all 2162 data = 0.0503, GOF 1.149. The non-hydrogen atoms were refined anisotropically, and hydrogen atoms were located by calculation except that H atoms of N(2) and N(9) in 1 were located by difference Fourier maps. In 1, the atom of C(2) is disordered, and the occupancies of C(2A)/C(2B) were assigned as 60% and 40%. In 2, one en ligand is disordered, and the occupancies of disordered N(3)-C(3)-C(4)-N(4)/N(4A)-C(4A)- C(3A)-N(3A) atoms were assigned as 50% and 50% respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.