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Volumn 170, Issue 2, 2005, Pages 195-201

Polymerization initiation and transient spectrometric studies of water-soluble and -insoluble tert-butyl aroylperbenzoates

Author keywords

Photoinitiators; Polymerization; tert Butyl aroylperbenzoates; Transient spectrometry

Indexed keywords

1 VINYL 2 PYRROLIDINONE; ACETONITRILE; ACRYLIC ACID; BENZOIC ACID DERIVATIVE; BENZOPHENONE DERIVATIVE; ESTER DERIVATIVE; TERT BUTYL AROYLPERBENZOATE DERIVATIVE; UNCLASSIFIED DRUG; WATER;

EID: 13944275249     PISSN: 10106030     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jphotochem.2004.07.022     Document Type: Article
Times cited : (5)

References (36)
  • 17
    • 0345910427 scopus 로고    scopus 로고
    • Photopolymerization fundamentals and applications
    • A.B. Scranton C.N. Bowman R.W. Peiffer (Eds.)
    • B. Chiou R.J. English S.A. Khan Photopolymerization fundamentals and applications. In: A.B. Scranton C.N. Bowman R.W. Peiffer (Eds.) Proceedings of the ACS Symposium Series, vol. 673 1997 150
    • (1997) Proceedings of the ACS Symposium Series , vol.673 , pp. 150
    • Chiou, B.1    English, R.J.2    Khan, S.A.3
  • 18
    • 13944280422 scopus 로고    scopus 로고
    • The reported value of the triplet energy of some of the BAPs (∼77 kcal/mol, Ref. [2]) is corrected
    • The reported value of the triplet energy of some of the BAPs (∼77 kcal/mol, Ref. [2]) is corrected
  • 21
    • 13944276087 scopus 로고    scopus 로고
    • 1 state of 2 yielded a lifetime of 1.2. ns
    • 1 state of 2 yielded a lifetime of 1.2. ns
  • 26
    • 13944277255 scopus 로고    scopus 로고
    • Oxygen-inhibition effects are common to free radicals. More so, the triplet states of BAPs are readily quenched by oxygen. Nevertheless, the reported polymerization data represent the results obtained without removing oxygen from the monomer
    • Oxygen-inhibition effects are common to free radicals. More so, the triplet states of BAPs are readily quenched by oxygen. Nevertheless, the reported polymerization data represent the results obtained without removing oxygen from the monomer
  • 32
    • 13944252243 scopus 로고    scopus 로고
    • Either the aroylbenzoyloxyl radical or a combination of the aroylbenzoyloxyl and aroylphenyl radicals initially forms when the BAPs dissociate by the cleavage of the O - O bond. Nevertheless, the aroylbenzoyloxyl radical could not be observed during our pump-probe or nano-second laser flash photolysis experiments. This issue has been addressed in detail in Ref. [4]
    • Either the aroylbenzoyloxyl radical or a combination of the aroylbenzoyloxyl and aroylphenyl radicals initially forms when the BAPs dissociate by the cleavage of the O - O bond. Nevertheless, the aroylbenzoyloxyl radical could not be observed during our pump-probe or nano-second laser flash photolysis experiments. This issue has been addressed in detail in Ref. [4]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.