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Volumn 68, Issue 22, 2003, Pages 8368-8372

Synthesis, Crystal Structures, and Laser Flash Photolysis of tert-Butyl Aroylperbenzoates

Author keywords

[No Author keywords available]

Indexed keywords

LASER FLASH PHOTOLYSIS (LFP);

EID: 0142227994     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo030168d     Document Type: Article
Times cited : (3)

References (32)
  • 1
    • 0142143737 scopus 로고    scopus 로고
    • Contribution No. 502 from the Center for Photochemical Sciences
    • Contribution No. 502 from the Center for Photochemical Sciences.
  • 3
    • 0142174563 scopus 로고    scopus 로고
    • Scranton, A. B., Bowman, C. N., Peiffer, R. W., Eds.; ACS Symposium Series 673; American Chemical Society: Washington, DC
    • (b) Lai, Y.; Quinn, E. T. In Photopolymerization Fundamentals and Applications; Scranton, A. B., Bowman, C. N., Peiffer, R. W., Eds.; ACS Symposium Series 673; American Chemical Society: Washington, DC, 1997; p 35.
    • (1997) Photopolymerization Fundamentals and Applications , pp. 35
    • Lai, Y.1    Quinn, E.T.2
  • 21
    • 0142205700 scopus 로고    scopus 로고
    • note
    • There may be considerable differences in the geometries of these molecules when they are in their solid state and in solution, especially because of the flexible nature of the appended perester moiety. However, the high quantum yield of O-O bond dissociation suggests that molecules assume appropriate geometries in their triplet states such that the activation energy in causing scission of the O-O bond is minimal. A flat geometry in their triplet states might be imagined in which case triplet energy dissipation may be very facile. Density functional theory (DFT) calculations on some of these molecules are in the process of being carried to obtain information about the structure of their triplet states.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.