Isoprene and its degradation products as strong ozone precursors in Insubria, Northern Italy

Atmospheric Environment

Volumn 36, Issue 24, 2002, Pages 3867-3879

  Duane, M ^a   Poma, B ^a   Rembges, D ^a   Astorga, C ^a   Larsen, B R ^a  

^a JOINT RESEARCH CENTRE   (Italy)

Author keywords

DNPH; Isoprene; Methylvinylketone; Ozone formation

Indexed keywords

FOG; FORMALDEHYDE; HYDROCARBONS; KETONES; NITRATES; PLANTS (BOTANY); SMOKE;

OZONE PRECURSORS;

OZONE;

2,4 DINITROPHENYLHYDRAZINE; ACROLEIN DERIVATIVE; FORMALDEHYDE; HYDRAZONE DERIVATIVE; ISOPRENE; KETONE DERIVATIVE; NITROUS OXIDE; VOLATILE ORGANIC COMPOUND;

AIR QUALITY; ISOPRENE; OZONE; PEROXYACETYL NITRATE; SMOG;

AIR QUALITY; AMBIENT AIR; ARTICLE; ATMOSPHERIC DEPOSITION; CONCENTRATION (PARAMETERS); CORRELATION ANALYSIS; DEGRADATION; FIELD EMISSION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ITALY; MASS SPECTROMETRY; OXIDATION; PRIORITY JOURNAL; SEASONAL VARIATION; SMOG;

ITALY;

EID: 0036695903     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(02)00359-X     Document Type: Article

References (54)

1. Altshuller A.P. PANs in the atmosphere. Journal of Air and Waste Management Association. 43:1993;121-1230.
2. Atkinson R. Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes. Journal of Physical and Chemical Reference Data. 26:1997;215-290.
3. Benjamin M.T., Winer A. Estimating the ozone forming potential of urban trees and shrubs. Atmospheric Environment. 32:1998;53-58.
4. Biesenthal T.A., Wu Q., Shepson P.B., Wiebe H.A., Anlauf K.G., MacKay G.I. A study of relationships between isoprene, its oxidation products, and ozone in the lower Fraser Valley, BC. Atmospheric Environment. 31:1997;2049-2058.
5. Biesenthal T.A., Bottenheim J.W., Shepson P.B., Li S.-M., Brickell P.C. The chemistry of biogenic hydrocarbons at a rural site in eastern Canada. Journal of Geophysical Research. 103(D19):1998;25487-25498.
6. Borbon A., Fontaine H., Veillerot M., Locoge N., Galloo J.C., Guillermo R. An investigation into the traffic-related fraction of isoprene at an urban location. Atmospheric Environment. 35:2001;3749-3760.
7. 3 and particlenitrate at a rural loacation in eastern Canada - relationships and implied ozone production efficiency. Journal of Geophysical Research. 101:1996;4189-4204.
8. Bottenheim J.W., Sirois A., Brice K.A., Gallant A.J. Five years of continous observations of PAN and ozone at a rural location in eastern Canada. Journal of Geophysical Research. 99:1994;5333-5352.
9. X mixtures. Atmospheric Environment. 28:1994;3359-3368.
10. Brice K.A., Penkett S.A., Atkins D.H.F., Sandalls F.J., Bamber D.J., Tuck A.F., Vaugan G. Atmospheric measurements of peroxyacetyl nitrate (PAN) in rural, south-east England. Seasonal variations, winter photochemistry, and long-range transport Atmospheric Environment. 18:1984;2601-2702.
11. Brice K.A., Bottenheim J.W., Anlauf K.A., Wiebe H.A. Long-term measurements of atmospheric peroxyacetyl nitrate (PAN) at rural sites in Ontario and Nova Scotia; seasonal variations, and long-range transport. Tellus. 40B:1988;408-425.
12. X. International Journal of Chemical Kinetics. 28:1996;497-530.
13. 8 non-methane hydrocarbon measurements in Copenhagen. concentrations, sources and emission estimates The Science of the Total Environment. 236:1999;163-171.
14. Christensen C.S., Hummelshoj P., Jensen N.O., Larsen B.R., Lohse C., Pilegaard K., Skov H. Flux determination of terpenes from a Spanish orange orchard using a new relaxed eddy accumulation system. Atmospheric Environment. 34A:2000;3057-3067.
15. Dollard G.J., Jones B.M.R., Davies T.J. Measurements of gaseous peroxide and PAN in rural southern England. Atmospheric Environment. 25A:1992;2039-2053.
16. 2 and PAN in a rural atmosphere. Environmental Pollution. 75:1992;45-52.
17. Fuentes J.D., Lerdau M., Atkinson R., Baldocchi D., Bottenheim J.W., Ciccioli P., Lamb B., Geron C., Gu L., Guenther A., Sharkey T.D., Stockwell W. Biogenic hydrocarbons in the atmospheric boundry layer. a review Bulletin of the American Meteorological Society. 81:2000;1537-1575.
18. 9 carbonyls in air. International Journal of Environmental Analytical Chemistry. 61:1995;343-360.
19. 10 carbonyls. International Journal of Environmental Analytical Chemistry. 61:1995;47-64.
20. Grosjean D., Williams E., Grosjean E. Atmospheric chemistry of isoprene and its carbonyl products. Environmental Science and Technology. 27:1993;830-840.
21. Grosjean E., Green P.G., Grosjean D. Liquid chromatography analysis of carbonyl (2,4-dinitrophenyl)hydrazones with detection by diode array ultraviolet spectroscopy and by atmospheric pressure negative chemical ionization mass spectrometry. Analytical Chemistry. 71:1999;1851-1861.
22. Guenther A., Zimmerman P., Harley P., Monson R., Fall R. Isoprene and monoterpene emission rate variability. model evaluation and sensitivity analysis Journal of Geophysical Research. 98:1993;12609-12617.
23. Guenther A., Hewitt C.N., Erickson D., Fall R., Geron C., Graedel T., Harley P., Klinger L., Lerdau M., Mckay W.A., Pierce T., Scholes B., Steinbrecher R., Tallamraju R., Taylor J., Zimmerman P. A global model of natural volatile organic compound emissions. Journal of Geophysical Research. 100(D5):1995;8873-8892.
24. Guicherit, R., 1988. Ozone on an urban and regional scale, with special reference to the situation in the Netherlands. In Isaksen, I.S.A. (ed.), Tropospheric ozone - Regional and Global scale interactions. Nato ASI series, Vol. 227, D. Riedel, Norwell, MA, pp. 49-62.
25. Hagerman L.M., Aneja V.P., Lonneman W.A. Characterisation of the non-methane hydrocarbons in the rural southeast United States. Atmospheric Environment. 31:1997;4017-4038.
26. Helmig D., Balsley B., Davis K., Kuck L.R., Jensen M., Bognar J., Smith T. Jr., Vasquez Arrieta R., Rodriguez R., Birks J.W. Vertical profiling and determination of landscape fluxes of biogenic nonmethane hydrocarbons within the planetary boundary layer in the Peruvian Amazon. Journal of Geophysical Research. 103(D19):1998;25519-25532.
27. Helmig D., Greenberg J., Guenther A., Zimmerman P., Geron C. Volatile organic compounds and isoprene oxidation products at a temperate deciduous forest site. Journal of Geophysical Research. 103(D17):1998;22397-22414.
28. Helmig D., Klinger L.F., Guenther A., Vierling L., Geron C., Zimmerman P. Biogenic volatile organic compound emissions (BVOCs). I. Identifications from three continental sites in the U.S. Chemosphere. 38:1999;2163-2187.
29. 5 alkanes and acetylene at a remote boral site in Canada. Journal of Geophysical Research. 99:1994;1589-1699.
30. Kolliker S., Oehme M., Dye C. Structure elucidation of 2,4-dinitrophenylhydrazone derivatives of carbonyl compounds in ambient air by HPLC/MS and multiple MS/MS using atmospheric chemical ionisation in the negative ion mode. Analytical Chemistry. 70:1998;1979-1985.
31. Kourtidis K.A., Fabian P., Zerefos C., Rappongluck B. Peroxypropionyl nitrate (PPN) and PAN/ozone ration measurements at three sites in Germany. Tellus. 45(B):1993;442-457.
32. 14C) measurements of carbonyl compounds in the atmosphere. quantifying the biogenic contribution Atmospheric Environment. 32:1998;1485-1492.
33. Larsen B.R., Tudos A., Slanina J., Borg K.v.d., Kotzias D. Quantification of airborne fossil and biomass carbonylic carbon by combined radiocarbon analysis and HPLC-MS. Atmospheric Environment. 35:2001;5695-5707.
34. Lee Y.-N., Zhou X., Kleinman L.I., Nunnermacker L.J., Springston S.R., Daum P.H., Newman L., Keigley W.G., Spicer C.W., Young V., Fu B., Parrish D.D., Holloway J., Williams J., Roberts J.M., Ryerson T.B., Fehsenfeld F.C. Atmospheric chemistry and distribution of formaldehyde and several multioxygenated carbonyl compounds during the 1995 Nashville/Middle Tennessee ozone study. Journal of Geophysical Research. 103(D17):1998;22449-22462.
35. Lenz, R., Köble, R., Seufert, G., 2001. Species-based mapping of biogenic emissions in Europe - case study, Italy. Proceedings of the Eighth European Symposium on the Physico-Chemical Behaviour of Atmospheric Pollutants, Torino, 17-20 September.
36. McClenny W.A., Daughtrey E.H. Jr., Adams J.R., Oliver K.D., Kronmiller K.G. Volatile organic compounds concentration patters at the New Hendersonville monitoring site in the 1995 southern oxidants study in the Nashville, Tennessee area. Journal of Geophysical Research. 103(D17):1998;22509-22518.
37. McLaren R., Singleton D.L., Lai J.Y.K., Khouw B., Singer E., Wu Z., Niki H. Analysis of motor vehicle sources and their contribution to ambient hydrocarbon distributions at urban sites in Toronto during the southern Ontario oxidants study. Atmospheric Environment. 30:1996;2119-2232.
38. Montzka S.A., Trainer M., Angevine W.M., Fehsenfeld F.C. Measurements of 3-methyl furan, methyl vinyl ketone, and methacrolein at a rural forested site in the southeastern United States. Journal of Geophysical Research. 100(D6):1995;11393-11401.
39. X-rich forest environment in the southeastern United States Journal of Geophysical Research. 103(D17):1998;22463-22471.
40. Pierotti D., Wofsy S.C., Jacob D., Rasmussen R.A. Isoprene and its oxidation products. methacrolein and methyl vinyl ketone Journal of Geophysical Research. 95(D2):1990;1871-1881.
41. Reimann S., Pierluigi C., Hofer P. The anthropogenic fraction contribution to isoprene concentration in a rural atmosphere. Atmospheric Environment. 34:2000;109-115.
42. Rembges, D., Fantechi, G., Dutaur, L., Brun, C., 1999. AIRMON, Annual report 1999. European Commission, Joint Research Centre-Ispra, Environment Institute, 21021-VA Italy. EUR 19665 EN.
43. 3 measurements. Fresenius Environment Bulletin. 9:2000;186-192.
44. Rembges, D., et al., 2001a. AIRMON, Annual Report 2000/2001. European Commission, Joint Research Centre-Ispra, Environment Institute, 21021-VA Italy. EUR 20011 EN.
45. Rembges, D., Duane, M., Hjorth, J., Bloem, H., Zaaiman, W., Larsen, B.R., 2001b. PAN and air quality in northern Italy: diurnal variation and long-term trends. Proceedings of the Eighth European Symposium on the Physico-Chemical Behaviour of Atmospheric Pollutants, Torino, 17-20 September, 2001.
46. Simon V., Luchetta L., Torres L. Estimating the emission of volatile organic compounds (VOC) from the French forest ecosystem. Atmospheric Environment. 35(S1):2001;115-126.
47. Simpson D., Winiwarter W., Börjesson G., Cinderby S., Ferreiro A., Guenther A., Hewitt C.N., Janson R., Khalil M.A.K., Owen S., Pierce T.E., Puxbaum H., Shearer M., Skiba U., Steinbrecher R., Tarrasón L., Öquist M.G. Inventorying emissions from nature in Europe. Journal of Geophysical Research. 104:1999;8113-8152.
48. Solberg S., Dye C., Walker S.-E., Simpson D. Long-term measurements and model calculations of formaldehyde at rural European monitoring sites. Atmospheric Environment. 35:2001;195-207.
49. Starn T.K., Shepson P.B., Bertman S.B., Riemer D.D., Zika R.G., Olszyna K. Nighttime isoprene chemistry at an urban-impacted forested site. Journal of Geophysical Research. 103(D17):1998;22437-22447.
50. Starn T.K., Shepson P.B., Bertman S.B., White J.S., Splawn B.G., Riemer D.D., Zika R.G., Olszyna K. Observations of isoprene chemistry and its role in ozone production at a semirural site during the 1995 southern oxidants study. Journal of Geophysical Research. 103(D17):1998;22425-22435.
51. Stroud C.A., Roberts J.M., Goldan P.D., Kuster W.C., Murphy P.C., Williams E.J., Hereid D., Parrish D., Sueper D., Trainer M., Fehsenfeld F.C., Apel E.C., Riemer D., Wert B., Henry B., Fried A., Martinez-Harder M., Harder H., Brune W.H., Li G., Xie H., Young V.L. Isoprene and its oxidation products methacrolein and methylvinyl ketone, at an urban forested site during 1999 southern oxidants study. Journal of Geophysical Research. 106(D18):2001;8035-8046.
52. Wiedinmyer C., Friedfeld S., Baugh W., Greenberg J., Guenther A., Fraser M., Allen D. Measurement and analysis of atmospheric concentrations of isoprene and its reaction products in central Texas. Atmospheric Environment. 35:2001;1001-1013.
53. Yokouchi Y. Seasonal and diurnal variation of isoprene and its reaction products in a semi-rural area. Atmospheric Environment. 28:1994;2651-2658.
54. Young, V.L., Kieser, B.N., Chen, S.P., Niki., 1997. Seasonal trends and local influences on non-methane hydrocarbons in the Canadian boral forest. Journal of Geophysical Research 102(D5), 5913-5918.