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Volumn 7, Issue 3, 2005, Pages 491-493

Iron-catalyzed oxidative homo-coupling of aryl grignard reagents

Author keywords

[No Author keywords available]

Indexed keywords

DICHLOROETHANE; IRON DERIVATIVE; REAGENT;

EID: 13844254448     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol047509+     Document Type: Article
Times cited : (165)

References (36)
  • 31
    • 13844261975 scopus 로고    scopus 로고
    • note
    • In the iron-catalyzed Grignard cross-coupling, Fe(I), Fe(II), and Fe(-II) species are proposed as catalytically active species: see ref 12c and references therein.
  • 32
    • 13844274275 scopus 로고    scopus 로고
    • note
    • Generation of ethylene was confirmed by trapping the evolved gas with bromine, which gave 1,2-dibromoethane. See also ref 15.
  • 34
    • 0012397313 scopus 로고
    • For a recent review on directed ortho-metalation, see: Snieckus, V. Chem. Rev. 1990, 90, 879.
    • (1990) Chem. Rev. , vol.90 , pp. 879
    • Snieckus, V.1
  • 36
    • 13844274273 scopus 로고    scopus 로고
    • note
    • Low yield was also observed in the homo-coupling of phenyllithium giving biphenyl (38% yield, ether reflux for 1 h).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.