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Volumn 4, Issue 1, 2005, Pages 106-112

Picosecond kinetics of excited-state charge separation in 4-(dimethylamino)pyridine

Author keywords

Electron donor acceptor systems; Intramolecular electron transfer; Picosecond kinetics

Indexed keywords

4 DIMETHYLAMINOPYRIDINE;

EID: 13444309519     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/b411627e     Document Type: Article
Times cited : (15)

References (46)
  • 1
    • 0001429474 scopus 로고
    • Fluoreszenzspectrum und Franck–Condon-prinzip in lösungen aromatischer verbindungen
    • A. Mangini, Pergamon Press, Oxford
    • E. Lippert, W. Lüder and H. Boss, Fluoreszenzspectrum und Franck–Condon-prinzip in lösungen aromatischer verbindungen, in Advances in Molecular Spectroscopy, ed. A. Mangini, Pergamon Press, Oxford, 1962, p. 443.
    • (1962) Advances in Molecular Spectroscopy , pp. 443
    • Lippert, E.1    Lüder, W.2    Boss, H.3
  • 2
    • 0142231517 scopus 로고    scopus 로고
    • Structural changes accompanying intramolecular electron transfer: Focus on twisted intramolecular charge transfer states and structures
    • Z. R. Grabowski K. Rotkiewicz W. Rettig Structural changes accompanying intramolecular electron transfer: focus on twisted intramolecular charge transfer states and structures Chem. Rev. 2003 103 3899.
    • (2003) Chem. Rev. , vol.103 , pp. 3899
    • Grabowski, Z.R.1    Rotkiewicz, K.2    Rettig, W.3
  • 4
    • 21844489225 scopus 로고
    • Excited charge transfer states in 4-aminopyrimidines, 4-(Dimethylanilino)pyrimidine and 4-(dimethylamino)pyridine
    • J. Herbich J. Waluk Excited charge transfer states in 4-aminopyrimidines, 4-(dimethylanilino)pyrimidine and 4-(dimethylamino)pyridine Chem. Phys. 1994 188 247.
    • (1994) Chem. Phys. , vol.188 , pp. 247
    • Herbich, J.1    Waluk, J.2
  • 5
    • 0035797209 scopus 로고    scopus 로고
    • Dual fluorescence of 4-dimethylaminopyridine and its derivatives. Effects of methyl substitution at the pyridine ring
    • S. Mishina M. Takayanagi M. Nakata J. Otsuki K. Araki Dual fluorescence of 4-dimethylaminopyridine and its derivatives. Effects of methyl substitution at the pyridine ring J. Photochem. Photobiol. Chem. A 2001 141 153.
    • (2001) J. Photochem. Photobiol. Chem. A , vol.141 , pp. 153
    • Mishina, S.1    Takayanagi, M.2    Nakata, M.3    Otsuki, J.4    Araki, K.5
  • 8
    • 49549163667 scopus 로고
    • Reinterpretation of the anomalous fluorescence of p-N, N-dimethylamino-benzonitrile
    • K. Rotkiewicz K. H. Grellmann Z. R. Grabowski Reinterpretation of the anomalous fluorescence of p-N, N-dimethylamino-benzonitrile Chem. Phys. Lett. 1973 19 315.
    • (1973) Chem. Phys. Lett. , vol.19 , pp. 315
    • Rotkiewicz, K.1    Grellmann, K.H.2    Grabowski, Z.R.3
  • 9
    • 0001335830 scopus 로고
    • Twisted intramolecular charge transfer states (TICT). A new class of excited states with a full charge separation
    • Z. R. Grabowski K. Rotkiewicz A. Siemiarczuk D. J. Cowley W. Baumann Twisted intramolecular charge transfer states (TICT). A new class of excited states with a full charge separation Nouv. J. Chim. 1979 3 443.
    • (1979) Nouv. J. Chim. , vol.3 , pp. 443
    • Grabowski, Z.R.1    Rotkiewicz, K.2    Siemiarczuk, A.3    Cowley, D.J.4    Baumann, W.5
  • 10
    • 84961472861 scopus 로고
    • Twisted intramolecular charge transfer (TICT) excited states: Energy and molecular structure
    • Z. R. Grabowski J. Dobkowski Twisted intramolecular charge transfer (TICT) excited states: energy and molecular structure Pure Appl. Chem. 1983 55 245.
    • (1983) Pure Appl. Chem. , vol.55 , pp. 245
    • Grabowski, Z.R.1    Dobkowski, J.2
  • 11
    • 0000406159 scopus 로고
    • Spectroscopy and kinetics of the twisted internal charge-transfer (TICT) excited state formation in p-substituted dialkylanilines
    • Z. R. Grabowski K. Rotkiewicz W. Rubaszewska E. Kirkor-Kaminska Spectroscopy and kinetics of the twisted internal charge-transfer (TICT) excited state formation in p-substituted dialkylanilines Acta Phys. Polonica A 1978 54 767.
    • (1978) Acta Phys. Polonica A , vol.54 , pp. 767
    • Grabowski, Z.R.1    Rotkiewicz, K.2    Rubaszewska, W.3    Kirkor-Kaminska, E.4
  • 12
    • 0019684541 scopus 로고
    • External and internal parameters affecting the dual fluorescence of p-cyano-dialkylanilines
    • W. Rettig External and internal parameters affecting the dual fluorescence of p-cyano-dialkylanilines J. Lumin. 1980 26 21.
    • (1980) J. Lumin. , vol.26 , pp. 21
    • Rettig, W.1
  • 13
    • 36749121289 scopus 로고
    • Picosecond dynamics of twisted internal charge transfer phenomena
    • Y. Wang K. B. Eisenthal Picosecond dynamics of twisted internal charge transfer phenomena J. Chem. Phys. 1982 77 6076.
    • (1982) J. Chem. Phys. , vol.77 , pp. 6076
    • Wang, Y.1    Eisenthal, K.B.2
  • 14
    • 0039414695 scopus 로고
    • Complex kinetics of a* state formation in the DMABN-ethanol system
    • S. R. Meech D. Phillips Complex kinetics of a* state formation in the DMABN-ethanol system Chem. Phys. Lett. 1985 116 262.
    • (1985) Chem. Phys. Lett. , vol.116 , pp. 262
    • Meech, S.R.1    Phillips, D.2
  • 15
    • 33751499945 scopus 로고
    • Intramolecular charge transfer and thermal exciplex dissociation with p-aminobenzonitriles in toluene
    • U. Leinhos W. Kühnle K. A. Zachariasse Intramolecular charge transfer and thermal exciplex dissociation with p-aminobenzonitriles in toluene J. Phys. Chem. 1991 95 2013.
    • (1991) J. Phys. Chem. , vol.95 , pp. 2013
    • Leinhos, U.1    Kühnle, W.2    Zachariasse, K.A.3
  • 16
    • 0001407795 scopus 로고
    • Excited-state dipole moments of dual fluorescent 4-(Dialkylamino)benzonitriles. Influence of alkyl chain length and effective solvent polarity
    • W. Schuddeboom S. A. Jonker J. M. Warman U. Leinhos W. Kühnle K. A. Zachariasse Excited-state dipole moments of dual fluorescent 4-(dialkylamino)benzonitriles. Influence of alkyl chain length and effective solvent polarity J. Phys. Chem. 1992 96 10809.
    • (1992) J. Phys. Chem. , vol.96 , pp. 10809
    • Schuddeboom, W.1    Jonker, S.A.2    Warman, J.M.3    Leinhos, U.4    Kühnle, W.5    Zachariasse, K.A.6
  • 18
    • 0037139561 scopus 로고    scopus 로고
    • An experimental test of C–N bond twisting in the TICT state: Syn-anti photoisomerization in 2-(N-methyl-N-isopropylamino)-5-cyanopyridine
    • J. Dobkowski J. Wójcik W. Koźmiński R. Kołos J. Waluk J. Michl An experimental test of C–N bond twisting in the TICT state: syn-anti photoisomerization in 2-(N-methyl-N-isopropylamino)-5-cyanopyridine J. Am. Chem. Soc. 2002 124 2406.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 2406
    • Dobkowski, J.1    Wójcik, J.2    Koźmiński, W.3    Kołos, R.4    Waluk, J.5    Michl, J.6
  • 19
    • 0000610371 scopus 로고
    • Picosecond absorption spectra of carbonyl derivatives of dimethylaniline: The nature of the TICT excited states
    • C. Rullière Z. R. Grabowski J. Dobkowski Picosecond absorption spectra of carbonyl derivatives of dimethylaniline: the nature of the TICT excited states Chem. Phys. Lett. 1987 137 408.
    • (1987) Chem. Phys. Lett. , vol.137 , pp. 408
    • Rullière, C.1    Grabowski, Z.R.2    Dobkowski, J.3
  • 20
    • 0012736873 scopus 로고
    • Excited-state dynamics of ethyl 4-(N, N-dimethylamino)benzoate and ethyl 4-(N, N-diethylamino)benzoate in apolar and polar solvents
    • P. C. M. Weisenborn A. H. Huizer C. A. G. O. Varma Excited-state dynamics of ethyl 4-(N, N-dimethylamino)benzoate and ethyl 4-(N, N-diethylamino)benzoate in apolar and polar solvents J. Chem. Soc., Faraday Trans. 2 1989 85 1895.
    • (1989) J. Chem. Soc., Faraday Trans. 2 , vol.85 , pp. 1895
    • Weisenborn, P.C.M.1    Huizer, A.H.2    Varma, C.A.G.O.3
  • 21
    • 13444290248 scopus 로고
    • Unique properties of the lowest excited singlet state of 4-dialkylaminopyrimidines
    • J. B. Birks, Wiley, London
    • J. Smagowicz, K. Berens and K. L. Wierzchowski, Unique properties of the lowest excited singlet state of 4-dialkylaminopyrimidines, in Excited States of Biological Molecules, ed. J. B. Birks, Wiley, London, 1976, p. 24.
    • (1976) Excited States of Biological Molecules , pp. 24
    • Smagowicz, J.1    Berens, K.2    Wierzchowski, K.L.3
  • 22
    • 0000128807 scopus 로고
    • Dual fluorescence of 4-(Dialkylamino)pyrimidines. Twisted intramolecular charge transfer state formation favored by hydrogen bond or by coordination to the metal ion
    • J. Herbich Z. R. Grabowski H. Wójtowicz K. Golankiewicz Dual fluorescence of 4-(dialkylamino)pyrimidines. Twisted intramolecular charge transfer state formation favored by hydrogen bond or by coordination to the metal ion J. Phys. Chem. 1989 93 3439.
    • (1989) J. Phys. Chem. , vol.93 , pp. 3439
    • Herbich, J.1    Grabowski, Z.R.2    Wójtowicz, H.3    Golankiewicz, K.4
  • 23
    • 0000404667 scopus 로고
    • Modification of the intramolecular electron transfer by hydrogen bonding: 4-(dialkylamino)pyrimidines
    • J. Herbich J. Karpiuk Z. R. Grabowski N. Tamai K. Yoshihara Modification of the intramolecular electron transfer by hydrogen bonding: 4-(dialkylamino)pyrimidines J. Lumin. 1992 54 165.
    • (1992) J. Lumin. , vol.54 , pp. 165
    • Herbich, J.1    Karpiuk, J.2    Grabowski, Z.R.3    Tamai, N.4    Yoshihara, K.5
  • 24
    • 0000895811 scopus 로고
    • Considerations on organic compounds in solution and inorganic ions in glasses as fluorescent standard reference materials
    • Proc. Conf. NBS, National Bureau of Standards, Gaithersburg, MD
    • R. A. Velapoldi, Considerations on organic compounds in solution and inorganic ions in glasses as fluorescent standard reference materials, in National Bureau of Standards Special Publication 378, Accuracy in Spectrophotometry and Luminescence Measurements, Proc. Conf. NBS, National Bureau of Standards, Gaithersburg, MD, 1972, p. 231.
    • (1972) National Bureau of Standards Special Publication 378, Accuracy in Spectrophotometry and Luminescence Measurements , pp. 231
    • Velapoldi, R.A.1
  • 26
    • 0000169232 scopus 로고
    • An algorithm for least-squares estimation of nonlinear parameters
    • D. W. Marquardt An algorithm for least-squares estimation of nonlinear parameters J. Soc. Ind. Appl. Math. 1963 11 431.
    • (1963) J. Soc. Ind. Appl. Math. , vol.11 , pp. 431
    • Marquardt, D.W.1
  • 28
    • 0000238336 scopus 로고
    • A simplex method for function minimization
    • J. A. Nelder R. Mead A simplex method for function minimization Comput. J. 1965 7 308.
    • (1965) Comput. J. , vol.7 , pp. 308
    • Nelder, J.A.1    Mead, R.2
  • 32
    • 0346139159 scopus 로고
    • Simple pyrimidines. Part III. The methylation and structure of the aminopyrimidines
    • D. I. Brown E. Hoerger S. F. Mason Simple pyrimidines. Part III. The methylation and structure of the aminopyrimidines J. Chem. Soc. 1955 4035.
    • (1955) J. Chem. Soc. , pp. 4035
    • Brown, D.I.1    Hoerger, E.2    Mason, S.F.3
  • 33
    • 0016687173 scopus 로고
    • 2 and ortho-C methylation on protolytic equilibria and electronic absorption spectra
    • 2 and ortho-C methylation on protolytic equilibria and electronic absorption spectra Acta Biochim. Pol. 1975 22 131.
    • (1975) Acta Biochim. Pol. , vol.22 , pp. 131
    • Proba, Z.1    Wierzchowski, K.L.2
  • 34
    • 0041573625 scopus 로고
    • Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, π*, α and β and some methods for simplifying the generalized solvatochromic equation
    • M. J. Kamlet J.-L. M. Abboud M. H. Abraham R. W. Taft Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, π*, α and β and some methods for simplifying the generalized solvatochromic equation J. Org. Chem. 1983 48 2877.
    • (1983) J. Org. Chem. , vol.48 , pp. 2877
    • Kamlet, M.J.1    Abboud, J.-L.M.2    Abraham, M.H.3    Taft, R.W.4
  • 35
    • 4244109532 scopus 로고
    • Molecular structure and temperature-dependent radiative rates in twisted intramolecular charge transfer and exciplex system
    • M. Van der Auweraer Z. R. Grabowski W. Rettig Molecular structure and temperature-dependent radiative rates in twisted intramolecular charge transfer and exciplex system J. Phys. Chem. 1991 95 2084.
    • (1991) J. Phys. Chem. , vol.95 , pp. 2084
    • Van der Auweraer, M.1    Grabowski, Z.R.2    Rettig, W.3
  • 36
    • 21144479828 scopus 로고
    • Radiative electron transfer in aryl derivatives of dimethylanilines
    • J. Herbich A. Kapturkiewicz Radiative electron transfer in aryl derivatives of dimethylanilines Chem. Phys. 1993 170 221.
    • (1993) Chem. Phys. , vol.170 , pp. 221
    • Herbich, J.1    Kapturkiewicz, A.2
  • 37
    • 0032506973 scopus 로고    scopus 로고
    • Electronic structure an molecular conformation in the excited charge transfer singlet states of 9-acridyl and other aryl derivatives of aromatic amines
    • J. Herbich A. Kapturkiewicz Electronic structure an molecular conformation in the excited charge transfer singlet states of 9-acridyl and other aryl derivatives of aromatic amines J. Am. Chem. Soc. 1998 120 1014.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 1014
    • Herbich, J.1    Kapturkiewicz, A.2
  • 38
    • 0001156878 scopus 로고
    • Organic solvents
    • Wiley-Interscience, New York, 3rd edn
    • J. A. Riddick and W. B. Bunger, Organic solvents, in: Techniques of Chemistry, Wiley-Interscience, New York, 3rd edn., 1970, vol. 2.
    • (1970) Techniques of Chemistry , vol.2
    • Riddick, J.A.1    Bunger, W.B.2
  • 40
    • 0001873540 scopus 로고
    • Model compounds in study of the photophysical behaviour of carbonyl derivatives of N, N-dimethylaniline
    • Z. R. Grabowski J. Dobkowski W. Kühnle Model compounds in study of the photophysical behaviour of carbonyl derivatives of N, N-dimethylaniline J. Mol. Struct. 1984 114 93.
    • (1984) J. Mol. Struct. , vol.114 , pp. 93
    • Grabowski, Z.R.1    Dobkowski, J.2    Kühnle, W.3
  • 42
    • 37049113083 scopus 로고
    • A structure-reactivity relationship for the basicity of aza-arenes
    • J. Spanget-Larsen A structure-reactivity relationship for the basicity of aza-arenes J. Chem. Soc., Perkin Trans. 2 1985 417.
    • (1985) J. Chem. Soc., Perkin Trans. 2 , pp. 417
    • Spanget-Larsen, J.1
  • 43
    • 0029919480 scopus 로고    scopus 로고
    • Solvent-controlled excited state behaviour: 2-(2′-pyridyl)indoles in alcohols
    • J. Herbich C.-Y. Hung R. P. Thummel J. Waluk Solvent-controlled excited state behaviour: 2-(2′-pyridyl)indoles in alcohols J. Am. Chem. Soc. 1996 118 3508.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 3508
    • Herbich, J.1    Hung, C.-Y.2    Thummel, R.P.3    Waluk, J.4
  • 45
    • 0004184936 scopus 로고
    • Bd. II, 5 Teil, Springer Verlag
    • Landolt-Börnstein, Bd. II, 5 Teil, Springer Verlag, 1969, pp. 209–214.
    • (1969) Landolt-Börnstein , pp. 209-214
  • 46
    • 0001276203 scopus 로고
    • Reversible photophysical processes
    • J. B. Birks Reversible photophysical processes Nouv. J. Chim. 1977 1 453.
    • (1977) Nouv. J. Chim. , vol.1 , pp. 453
    • Birks, J.B.1


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