Synthesis of poly(2-substituted-1-propenylene)s from allylic arsonium ylides

Macromolecules

Volumn 38, Issue 3, 2005, Pages 663-668

  Mondière, Régis ^a   Goddard, Jean Philippe ^a   Carrot, Géraldine ^b   Le Gall, Thierry ^a   Mioskowski, Charles ^a,b  

^a CEA SACLAY   (France)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CARBON; CHEMICAL BONDS; POLYMERIZATION; POLYMERS; SALTS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

BORANE; CARBON CHAIN; CHAIN ELONGATION; MOLAR RATIO;

PROPYLENE;

EID: 13444258039     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma047693e     Document Type: Article

References (20)

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12. For reviews on arsonium ylides chemistry, see: (a) Smith, M. D. In Science of Synthesis; Fleming, I., Ed.; Georg Thieme Verlag: Stuttgart, 2002; Vol. 4, pp 13-51. (b) Lloyd, D.; Gosney, I.; Ormiston, R. A. Chem. Soc. Rev. 1987, 16, 45-74.
13. For reviews on arsonium ylides chemistry, see: (a) Smith, M. D. In Science of Synthesis; Fleming, I., Ed.; Georg Thieme Verlag: Stuttgart, 2002; Vol. 4, pp 13-51. (b) Lloyd, D.; Gosney, I.; Ormiston, R. A. Chem. Soc. Rev. 1987, 16, 45-74.
14. Another sample of polymer 3a has previously been prepared by this method (see ref 5) but was not characterized using size exclusion chromatography (SEC) at that time.
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19. In another experiment, the second ylide was added 5 min after the discoloration of the reaction mixture. In that case, the SEC pattern of the isolated polymer 9b showed a bimodal distribution. Thus, it is highly preferable to add the second ylide as soon as the first discoloration occurred.
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