Scope, mechanism and diene inhibition of isomerization of allylic alcohols to saturated ketones catalyzed by ruthenium(II)-cyclopentadienyl complexes

Journal of Organometallic Chemistry

Volumn 690, Issue 4, 2005, Pages 1044-1055

  Van Der Drift, Robert C ^a   Gagliardo, Marcella ^a   Kooijman, Huub ^b   Spek, Anthony L ^b   Bouwman, Elisabeth ^a   Drent, Eite ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Allylic alcohols; Cyclopentadienyl; Diene inhibition; Isomerization; Ruthenium

Indexed keywords

AMINES; CATALYSIS; COMPLEXATION; COORDINATION REACTIONS; ISOMERIZATION; KETONES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; OXYGEN; REACTION KINETICS; RUTHENIUM COMPOUNDS; X RAY DIFFRACTION;

ALLYLIC ALCOHOLS; NUCLEOPHILICITY; TERTIARY AMINES; TRIPHEYNYLPHOSPHINE;

ALCOHOLS;

2 BUTANONE; 3 BUTEN 2 OL; ALCOHOL; ALKADIENE; ALKENE; ALLYL COMPOUND; AMINE; BIS(DIPHENYLPHOSPHINO)BUTANE; BUTANE; CHEMICAL COMPOUND; DIBUTYLAMINE; HYDROGEN; KETONE; LIGAND; OXYGEN; PHOSPHINE; RUTHENIUM; RUTHENIUM COMPLEX; TRIPHENYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; BINDING AFFINITY; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION; INHIBITION KINETICS; ISOMERIZATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PRECURSOR; REACTION ANALYSIS; TIME; X RAY DIFFRACTION;

EID: 13444251180     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.11.017     Document Type: Article

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