2,3-Bifunctionalized Aziridines: Regioselective MgBr2-Mediated Opening under "Chelation Controlled" Conditions

Synthetic Communications

Volumn 34, Issue 1, 2004, Pages 85-97

  Righi, Giuliana ^a   Catullo, Simona ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

2,3 Bifuctionalized aziridines; Chelation control; MgBr2

Indexed keywords

2 BENZYLOXYMETHYL 1 TERT BUTOXYCARBONYL 3 FORMYLAZIRIDINE; 2 BENZYLOXYMETHYL 1 TERT BUTOXYCARBONYL 3 HYDROXYMETHYLAZIRIDINE; 3 BENZYLOXYMETHYL 1 TERT BUTOXYCARBONYL 2 METHOXYCARBONYLAZIRIDINE; 4 (2 BENZYLOXY 1 BROMOETHYL) 2,2 DIMETHYLOXAZOLIDINE 3 CARBOXYLIC ACID TERT BUTYL ESTER; 4 (2 BENZYLOXY 1 BROMOETHYL) 2,2,5 TRIMETHYLOXAZOLIDINE 3 CARBOXYLIC ACID TERT BUTYL ESTER; 4 BENZYLOXY 2 BROMO 3 [(N TERT BUTOXYCARBONYL)AMINO]BUTAN 1 OL; 4 BENZYLOXY 2 BROMO 3 [(N TERT BUTOXYCARBONYL)AMINO]BUTANOIC ACID METHYL ESTER; 4 BENZYLOXY 3 BROMO 2 [(N TERT BUTOXYCARBONYL)AMINO]BUTAN 1 OL; 4 BENZYLOXY 3 BROMO 2 [(N TERT BUTOXYCARBONYL)AMINO]BUTANOIC ACID METHYL ESTER; 5 BENZYLOXY 3 BROMO 4 [(N TERT BUTOXYCARBONYL)AMINO]PENTAN 2 OL; 5 BENZYLOXY 4 BROMO 3 [(N TERT BUTOXYCARBONYL)AMINO]PENTAN 2 OL; ALLYL ALCOHOL; AZIRIDINE DERIVATIVE; BROMINE DERIVATIVE; EPOXIDE; MAGNESIUM; MAGNESIUM BROMIDE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHELATION; PROTON NUCLEAR MAGNETIC RESONANCE; RING OPENING; STEREOCHEMISTRY; STEREOISOMERISM; THIN LAYER CHROMATOGRAPHY;

EID: 1342302765     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1081/SCC-120027242     Document Type: Article

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