Electrolysis of mixed melt of (CH3)4NF· mHF + x wt.% CsF·2.0HF with nickel anode

Electrochimica Acta

Volumn 49, Issue 13, 2004, Pages 2131-2137

  Shodai, Yoshio ^a   Inaba, Minoru ^a   Momota, Kunitaka ^b   Kimura, Tomotaka ^a   Tasaka, Akimasa ^a  

^a DOSHISHA UNIVERSITY   (Japan)

^b Morita Chemical Industries Co Ltd   (Japan)

Author keywords

Cesium nickel fluoride (CsNi2F6); Electrolytic perfluorination; Perfluorotrimethylamine (CF3)3N ; Room temperature molten salt

Indexed keywords

ANODES; ELECTRIC CONDUCTIVITY; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; ELECTROLYSIS; FUSED SALTS; GAS CHROMATOGRAPHY; IONIC CONDUCTION; MASS SPECTROMETRY; NICKEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; SYNTHESIS (CHEMICAL);

CESIUM NICKEL FLUORIDE (CSNI2F6); ELECTROLYTIC PERFLUORINATION; PERFLUOROTRIMETHYLAMINE [(CF3)3N]; ROOM TEMPERATURE MOLTEN SALTS;

FLUORINE COMPOUNDS;

EID: 1342285581     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2003.12.039     Document Type: Article

References (17)

1. Fukaya H., Ono T., Abe T. J. Comput. Chem. 19:1998;277.
2. H. Fukaya, T. Ono, T. Abe, J. Chem. Soc., Chem. Commun. (1995) 1207.
3. J.H. Simons, US Patent 2 616 927 (1952).
4. Bürger H., Niepel H., Pawelke G., Frohn H.J., Sartori P. J. Fluorine Chem. 15:1980;231.
5. Momota K. Molten Salts. 45:2002;42.
6. Momota K., Yonezawa T., Hayakawa Y., Kato K., Morita M., Matsuda Y. J. Appl. Electrochem. 25:1995;651.
7. Momota K., Mukai K., Kato K., Morita M. Electrochim. Acta. 43:1998;2503.
8. Tasaka A., Yachi T., Makino T., Hamano K., Kimura T., Momota K. J. Fluorine Chem. 97:1999;253.
9. Winsor R.V., Cady G.H. J. Am. Chem. Soc. 70:1948;1500.
10. Tasaka A., Tsukuda Y., Yamada S., Matsushima K., Kohmura A., Muramatsu N., Takebayashi H., Mimaki T. Electrochim. Acta. 44:1999;1761.
11. Y. Shodai, K. Momota, A. Tasaka, Molten Salt XIII, PV 2002-19, The Electrochemical Society Proceedings Series, Pennington, NJ, 2002, 946 pp.
12. Watanabe N., Haruta M. Electrochim. Acta. 25:1979;461.
13. N. Ikeo, Y. Iijima, N. Nimura, M. Sigematsu, T. Tazawa, S. Matsumoto, K. Kojima, Y. Nagasawa, JEOL, Handbook of X-ray Photoelectron Spectroscopy, Appendix B, Chemical States Tables, Perkin-Elmer Corporation, pp. 220, 230.
14. Sartori P., Ignat'ev N. J. Fluorine Chem. 87:1998;157.
15. Tasaka A., Kawagoe T., Takuwa A., Yamanaka M. J. Electrochem. Soc. 145:1998;1160.
16. Tasaka A., Suzuki Y., Sakaguchi S., Fukuda N., Tojo T. Electrochim. Acta. 46:2001;4349.
17. Žemva B., Lutar K., Chacón L., Beuermann M.F., Allman J., Shen C., Bartlett N. J. Am. Chem. Soc. 117:1995;10025.