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We have recently published a discussion of dendritic effects on gel-phase materials and proposed that they rely on a subtle balance between additional favourable interactions at higher generation (such as hydrogen bonds) and unfavourable features such as greater steric repulsion and entropic cost of network formation when using more complex dendritic building blocks. A. R. Hirst and D. K. Smith, Org. Biomol. Chem., 2004, 2, 2965-2971.
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4043163395
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We have previously struggled to get SEM images of higher generation one-component dendritic gels - we postulated a flattened morphology which was difficult to image. C. S. Love, A. R. Hirst, V. Chechik, D. K. Smith, I. Ashworth and C. Brennan, Langmuir, 2004, 20, 6580-6585.
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22
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13244260399
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note
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Circular dichroism was not performed on dendron 1 in cyclohexane owing to its poor solubility and the formation of cloudy/opaque gels.
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