Lifetimes of polystyrene chains in atom transfer radical polymerization

Macromolecules

Volumn 32, Issue 26, 1999, Pages 9051-9053

  Matyjaszewski, Krzysztof ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE COMPOUNDS; CATALYST DEACTIVATION; COPPER COMPOUNDS; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; MONOMERS; RATE CONSTANTS;

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP);

POLYSTYRENES;

EID: 12944257374     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma991145x     Document Type: Article

References (22)

1. Matyjaszewski, K. In Controlled Radical Polymerization; Matyjaszewski, K., Ed.; American Chemical Society: Washington, DC, 1998; Vol. 685, p 258.
2. Wang, J. S.; Matyjaszewski, K. J Am. Chem. Soc. 1995, 117, 5614.
3. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
4. Matyjaszewski, K. Macromolecules 1998, 31, 4710.
5. Patten, T. E.; Matyjaszewski, K. Adv. Mater. 1998, 10, 901.
6. Patten, T. E.; Matyjaszewski, K. Acc. Chem. Res. 1999, 32, 895.
7. Matyjaszewski, K. Chem.-Eur. J. 1999, 5, 3095.
8. Matyjaszewski, K.; Patten, T.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674.
9. Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866.
10. Hathaway, B. J. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McClaverty, J. A., Eds; Pergamon: Oxford, England, 1987; Vol. 5, p 533.
11. Wang, J. L.; Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 6507.
12. Davis, K. A.; Paik, H. J.; Matyjaszewski, K. Macromolecules 1999, 32, 1767.
13. 2 anion. In such a case the rate constant of activation may be twice as large as that reported in ref 14, and the amount of activator twice as small as the [Cu(I)] species originally used. Nevertheless, under such conditions the rate of activation and lifetimes remain the same. Reactivity of the anion is much lower than that of the cation which can be solely responsible for the activation process (cf. ref 8).
14. Ohno, K.; Goto, A.; Fukuda, T.; Xia, J.; Matyjaszewski, K. Macromolecules 1998, 31, 2699.
15. Kajiwara, A.; Matyjaszewski, K. Macromolecules 1998, 31, 548.
16. Buback, M.; Gilbert, R. G.; Hutchinson, R. A.; Klumperman, B.; Kuchta, F.-D.; Manders, B. G.; O'Driscoll, K. F.; Russell, G. T.; Schweer, J. Macromol. Chem. Phys. 1995, 196, 3267.
17. Fischer, H.; Paul, H. Acc. Chem. Res. 1987, 20, 200.
18. Shipp, D. A.; Matyjaszewski, K. Macromolecules 1999, 32, 2948.
19. Russell, G. T. Macromol. Theory Simul. 1994, 3, 439.
20. Shipp, D. A.; Wang, J.-L.; Grimaud, T.; Matyjaszewski, K. Polym. Prepr. 1998, 39 (2), 504.
21. Kajiwara, A.; Matyjaszewski, K. Polym. J. 1999, 31 (1), 70.
22. Lyons, R. A.; Hutovic, J.; Piton, M. C.; Christie, D. I.; Clay, P. A.; Manders, B. G.; Kable, S. H.; Gilbert, R. G. Macromolecules 1996, 29, 9, 1918.