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note
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2, J(HH) = 7.2 Hz), 8.28 (s, 1 H, H5 (Im)), 8.38 (s, 1 H, H4 (Im)), 10.02 (s, 1 H, H2 (Im)). Procedure for the preparation of cocrystal of PD 1: 1-methyl-3-n-butyl imidazolium bromide (0.30 g, 0.0014 mol) and 1,4-phenylenediamine (0.15 g, 0.0014 mol) were put into the three-necked flask. The mixture was heated to 140°C under inert flow with stirring. After complete dilution of components, the reaction mass was cooled to room temperature forming brown crystals. DSC measurements were carried out using Mettler 822 with heat grade equal to 10°C/min.
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12844283560
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note
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2 = 0.1000 and GOF = 1.028 for all independent reflections (R1 = 0.0487 was calculated against F for 2506 observed reflections with I > 2σ(I)). All calculations were performed using SHELXTL PLUS 5.1.
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