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Volumn 14, Issue 3, 2003, Pages 235-252

Synthesis, characterization, and physical properties of two trinuclear, mixed-valence species of type [μ3-OMnIIMn 2III(O2CCF3)6(R) 3] (R = H2O, CH3COOH)

Author keywords

Antiferromagnetic coupling; EPR; Magnetic modeling; Manganese; Mass spectrometry

Indexed keywords

MANGANESE DERIVATIVE;

EID: 1242312509     PISSN: 10407278     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:JOCL.0000005061.56743.70     Document Type: Article
Times cited : (17)

References (63)
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    • Mn(III), was chosen based on experimental values previously reported: (a) B. J. Kennedy and K. S. Murray (1985). Inorg. Chem. 24, 1552-1557. (b) A.-L. Barra, D. Gatteschi, R. Sessoli, G. L. Abbati, A. Cornia, A. C. Fabretti, and M. G. Uytterhoeven (1997). Angew. Chem. Int. Ed. 36, 2329-2331. (c) J. Krzystek, J. Telser, L. Pardi, D. P. Goldberg, B. M. Hoffman, and L.-C. Brunel (1999). Inorg. Chem. 38, 6121-6129.
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    • note
    • -1 (R = 0.97). However, a closer examination of the parameters revealed that they correspond to the incorrect ground state of S = 1/2, thus the model does not lead to a global minimum. This became obvious upon modeling of the magnetization data, which was extremely poor.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.