Influence of the degree of ionization on weak polyelectrolyte multilayer assembly

Macromolecules

Volumn 38, Issue 1, 2005, Pages 116-124

  Choi, Jeeyoung ^a   Rubner, Michael F ^a  

^a Massachusetts Institute of Technology Cambridge   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BILAYERS; CHARGE DENSITY; MULTILAYER ASSEMBLY; MULTILAYER FILMS;

FOURIER TRANSFORM INFRARED SPECTROSCOPY; IONIZATION; MULTILAYERS; NEGATIVE IONS; PH EFFECTS; THIN FILMS;

POLYELECTROLYTES;

EID: 12344334998     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma048596o     Document Type: Article

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45. When a fully charged polyelectrolyte adsorbs onto a multilayer with a nonfully ionized weak polyelectrolyte as the outermost layer, the degree of ionization of the weak polyelectrolyte can increase by as much as an additional 10% (see ref 6). This effect becomes smaller as a weak polyelectrolyte chain approaches full ionization since the more ionized a weak polyelectrolyte becomes, the harder it is for the chain to be ionized (see refs 43 and 44).
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