Some mixed transition metal compounds of 1,3-diyne with metallacycles derived by cross-coupling of alkynyl ligands and sequential C-C bond coupling between 1,3-diyne and carbon monoxide

Organometallics

Volumn 24, Issue 1, 2005, Pages 20-27

  Yamazaki, Shinsaku ^a   Taira, Zenei ^b   Yonemura, Toshiaki ^c   Deeming, Anthony J ^d  

^a Kochi Gakuen College   (Japan)

^b TOKUSHIMA BUNRI UNIVERSITY   (Japan)

^c KOCHI UNIVERSITY   (Japan)

^d UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CHEMICAL BONDS; HALOGENATION; NONLINEAR OPTICS; STOICHIOMETRY; SYNTHESIS (CHEMICAL); TRANSITION METAL COMPOUNDS;

BOND COUPLING; LIGANDS; OXIDIZING REAGENTS;

AROMATIC COMPOUNDS;

EID: 12344324622     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0492754     Document Type: Article

References (60)

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48. 3): δ (ppm) 227.8{Fe-CO}, 220.6{Fe-CO), 219.7{Pt-CO}, 216.54{Pt-CO}, 83.0{PhC(Pt)-C(Pt)-C-CPh}, 98.4{PhC(Pt)-C(Pt)-CCPh), 146.0{PhC-C-C(Pt)-C(Pt)-Ph}, 166.0{PhC-C-C(Pt)-C (Pt)Ph}.
49. 195Pt satellites not discerned).
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54. 0) refining 550 parameters. Selected distances (A) and angles (deg): Pt(1)-P(2) 2.280(3), Pt(1)-P(3) 2.285(3), Pt(1)-C(6) 2.055(12), Pt(1)-C(9) 2.023(13), C(6)-C(9) 1.302(18), C(6)-C(30) 1.433(18), C(9)-C(17) 1.467(19), P(2)-Pt(1)-P(3) 105.2(1), P(2)-Pt(1)-C(9) 107.3(4), C(6)-Pt(1)-C(9) 37.2(5), C(6)-Pt(1)-P(3) 110.6(4), C(9)-C(6)-C(30) 143.4(13), C(6)-C(9)-C(17) 141.2(12).
55. Adams, R. D.; Wunz, U. H. F.; Captain, B.; Fu, W.; Steffen, W. J. Organomet. Chem. 2000, 614-615, 75.
56. 3, 6c or iso-6c}, 216.7{Pt-CO, 6c or iso-6c), 165.2{(Pt)-C(Ph)=C(Ph)-(Pt), 6c or iso-6c}, 150{(Pt)-C(Ph) C(Ph)-(Pt), 6c or iso-6c}.
57. 0) refining 521 parameters. Selected bond distances (A) and angles (deg): Pt(1)-Pt(2) 2.998(2) Pt(1)-Fe(1) 2.640(3) Pt-(2)-Fe(1) 2.605(4) Pt(1)-C(1) 2.09(2) Pt(2)-C(2) 2.04(3) Fe(1)-C(1) 2.10(2) Fe(1)-C(2) 2.11(2) C(1)-C(2) 1.44(4) Pt(1)-Pt(2)-C(2) 66.3(7) Pt(2)-Pt(1)-C(1) 69.2(7).
58. o) refining 561 parameters at 293(2) K. Selected bond distances (A) and angles (deg): Pt(1)-Pt(2) 3.056(2) Pt(1)-Fe(1) 2.567(4) Pt(2)-Fe(1) 2.643(4) Pt(1)-C(1) 2.08(3) Pt(2)-C(2) 1.98(2) Fe(1)-C(1) 2.10(3) Fe(1)-C(2) 2.04(3) C(1)-C(2) 1.42(4) Pt(1)-Pt(2)-C(2) 68.4(8) Pt(2)-P(1)-C(1) 63.7(8).
59. o) refining 550 parameters. Selected bond distances (A) and angles (deg): Pt(1)-Pt(2) 2.981(1), Pt(1)-Fe(1) 2.579(3), Pt(2)-Fe(1) 2.567-(3), Pt(1)-C(1) 2.014(17), Pt(2)-C(2) 2.021(17), Fe(1)-C(1) 2.069(17), Fe(1)-C(2) 2.053(17), C(1)-C(2) 1.42(3), Pt(1)-Pt(2)-C(2) 67.7(5), Pt-(2)-Pt(1)-C(1) 66.9(5).
60. p.c = 4.52 Hz}.